Crystallization behavior of Cu2ZnSn(Sx, Se1-x)4 absorbers processed from sputtered Cu2ZnSnS4 precursors under different selenization conditions

Solange Temgoua; Romain Bodeux; Sebastien Delbos; Negar Naghavi

doi:10.1109/PVSC.2014.6925417

Crystallization behavior of Cu₂ZnSn(S_x, Se_1-x)₄ absorbers processed from sputtered Cu₂ZnSnS₄ precursors under different selenization conditions

Solange Temgoua
, Romain Bodeux
, Sebastien Delbos
, Negar Naghavi

Institut Photovoltaïque d'Ile-de-France

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Citation (Scopus)

Abstract

In this work, we study the crystallization behavior of Cu₂ZnSn(S_xSe_1-x)₄ in annealing conditions. Cu-Zn-Sn-S precursors are deposited on glass/Mo substrate by a cosputtering of Cu, ZnS, and SnS. In order to have a better understanding of annealing on the mechanisms of formation of CZTSSe and secondary phases, these precursors are annealed at different temperatures (250°C <T<600°C), duration (1 to 60 min) and Se quantity. Efficiencies up to 7% are obtained. Material and diode properties are extracted from chemical, structural and opto-electronic characterization.

Original language	English
Title of host publication	2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	2425-2427
Number of pages	3
ISBN (Electronic)	9781479943982
DOIs	https://doi.org/10.1109/PVSC.2014.6925417
Publication status	Published - 15 Oct 2014
Event	40th IEEE Photovoltaic Specialist Conference, PVSC 2014 - Denver, United States Duration: 8 Jun 2014 → 13 Jun 2014

Publication series

Name	2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014

Conference

Conference	40th IEEE Photovoltaic Specialist Conference, PVSC 2014
Country/Territory	United States
City	Denver
Period	8/06/14 → 13/06/14

Keywords

CuZnSn(S,Se)
annealing
kesterite

Access to Document

10.1109/PVSC.2014.6925417

Cite this

Temgoua, S., Bodeux, R., Delbos, S., & Naghavi, N. (2014). Crystallization behavior of Cu₂ZnSn(S_x, Se_1-x)₄ absorbers processed from sputtered Cu₂ZnSnS₄ precursors under different selenization conditions. In 2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014 (pp. 2425-2427). Article 6925417 (2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC.2014.6925417

Temgoua, Solange ; Bodeux, Romain ; Delbos, Sebastien et al. / Crystallization behavior of Cu₂ZnSn(S_x, Se_1-x)₄ absorbers processed from sputtered Cu₂ZnSnS₄ precursors under different selenization conditions. 2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014. Institute of Electrical and Electronics Engineers Inc., 2014. pp. 2425-2427 (2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014).

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title = "Crystallization behavior of Cu2ZnSn(Sx, Se1-x)4 absorbers processed from sputtered Cu2ZnSnS4 precursors under different selenization conditions",

abstract = "In this work, we study the crystallization behavior of Cu2ZnSn(SxSe1-x)4 in annealing conditions. Cu-Zn-Sn-S precursors are deposited on glass/Mo substrate by a cosputtering of Cu, ZnS, and SnS. In order to have a better understanding of annealing on the mechanisms of formation of CZTSSe and secondary phases, these precursors are annealed at different temperatures (250°C ",

keywords = "CuZnSn(S,Se), annealing, kesterite",

author = "Solange Temgoua and Romain Bodeux and Sebastien Delbos and Negar Naghavi",

note = "Publisher Copyright: {\textcopyright} 2014 IEEE.; 40th IEEE Photovoltaic Specialist Conference, PVSC 2014 ; Conference date: 08-06-2014 Through 13-06-2014",

year = "2014",

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doi = "10.1109/PVSC.2014.6925417",

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series = "2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014",

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Temgoua, S, Bodeux, R, Delbos, S & Naghavi, N 2014, Crystallization behavior of Cu₂ZnSn(S_x, Se_1-x)₄ absorbers processed from sputtered Cu₂ZnSnS₄ precursors under different selenization conditions. in 2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014., 6925417, 2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014, Institute of Electrical and Electronics Engineers Inc., pp. 2425-2427, 40th IEEE Photovoltaic Specialist Conference, PVSC 2014, Denver, United States, 8/06/14. https://doi.org/10.1109/PVSC.2014.6925417

Crystallization behavior of Cu₂ZnSn(S_x, Se_1-x)₄ absorbers processed from sputtered Cu₂ZnSnS₄ precursors under different selenization conditions. / Temgoua, Solange; Bodeux, Romain; Delbos, Sebastien et al.
2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014. Institute of Electrical and Electronics Engineers Inc., 2014. p. 2425-2427 6925417 (2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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Temgoua S, Bodeux R, Delbos S, Naghavi N. Crystallization behavior of Cu₂ZnSn(S_x, Se_1-x)₄ absorbers processed from sputtered Cu₂ZnSnS₄ precursors under different selenization conditions. In 2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014. Institute of Electrical and Electronics Engineers Inc. 2014. p. 2425-2427. 6925417. (2014 IEEE 40th Photovoltaic Specialist Conference, PVSC 2014). doi: 10.1109/PVSC.2014.6925417