Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Sharanjeet K. Bagal; Michiel De Greef; Samir Z. Zard

doi:10.1021/ol052634m

Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Sharanjeet K. Bagal
, Michiel De Greef
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

(Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.

Original language	English
Pages (from-to)	147-150
Number of pages	4
Journal	Organic Letters
Volume	8
Issue number	1
DOIs	https://doi.org/10.1021/ol052634m
Publication status	Published - 5 Jan 2006
Externally published	Yes

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title = "Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent",

abstract = "(Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.",

author = "Bagal, \{Sharanjeet K.\} and \{De Greef\}, Michiel and Zard, \{Samir Z.\}",

year = "2006",

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doi = "10.1021/ol052634m",

language = "English",

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pages = "147--150",

journal = "Organic Letters",

issn = "1523-7060",

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T1 - Cyano(ethoxycarbonothioylthio)methyl benzoate

T2 - A novel one-carbon radical equivalent

AU - Bagal, Sharanjeet K.

AU - De Greef, Michiel

AU - Zard, Samir Z.

PY - 2006/1/5

Y1 - 2006/1/5

N2 - (Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.

AB - (Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study.

U2 - 10.1021/ol052634m

DO - 10.1021/ol052634m

M3 - Article

AN - SCOPUS:30944453036

SN - 1523-7060

VL - 8

SP - 147

EP - 150

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Abstract

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