Cyclizations and intermolecular additions of alkoxycarbonyloxy radicals from N-hydroxypyridine-2-thione carbonates

Martin Newcomb; M. Udaya Kumar; Jean Voivin; Elisabeth Crépon (née daSilva); Samir Z. Zard

doi:10.1016/S0040-4039(00)71214-7

Cyclizations and intermolecular additions of alkoxycarbonyloxy radicals from N-hydroxypyridine-2-thione carbonates

Martin Newcomb
, M. Udaya Kumar
, Jean Voivin
, Elisabeth Crépon (née daSilva)
, Samir Z. Zard

Research output: Contribution to journal › Article › peer-review

Abstract

Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.

Original language	English
Pages (from-to)	45-48
Number of pages	4
Journal	Tetrahedron Letters
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/S0040-4039(00)71214-7
Publication status	Published - 1 Jan 1991
Externally published	Yes

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title = "Cyclizations and intermolecular additions of alkoxycarbonyloxy radicals from N-hydroxypyridine-2-thione carbonates",

abstract = "Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.",

author = "Martin Newcomb and \{Udaya Kumar\}, M. and Jean Voivin and \{Cr{\'e}pon (n{\'e}e daSilva)\}, Elisabeth and Zard, \{Samir Z.\}",

year = "1991",

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doi = "10.1016/S0040-4039(00)71214-7",

language = "English",

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T1 - Cyclizations and intermolecular additions of alkoxycarbonyloxy radicals from N-hydroxypyridine-2-thione carbonates

AU - Newcomb, Martin

AU - Udaya Kumar, M.

AU - Voivin, Jean

AU - Crépon (née daSilva), Elisabeth

AU - Zard, Samir Z.

PY - 1991/1/1

Y1 - 1991/1/1

N2 - Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.

AB - Alkoxycarbonyloxy radicals from allyl and homoallyl alcohols cyclize in an exo fashion to give, respectively, 3-substituted 1,2-diol carbonates and 4-substituted 1,3-diol carbonates whereas simple alkoxycarbonyloxy radicals add intermolecularly to ethyl vinyl ether to give, ultimately, carbonates of glycolaldehyde derivatives.

U2 - 10.1016/S0040-4039(00)71214-7

DO - 10.1016/S0040-4039(00)71214-7

M3 - Article

AN - SCOPUS:0026026945

SN - 0040-4039

VL - 32

SP - 45

EP - 48

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 1

ER -

Cyclizations and intermolecular additions of alkoxycarbonyloxy radicals from N-hydroxypyridine-2-thione carbonates

Abstract

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