De novo simulation and spectroscopic study of iron speciation in ZSM-5 and CIT-5

  • P. P.H.J.M. Knops-Gerrits
  • , W. A. Goddard

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

The introduction of iron in the lattice of zeolite topologies, e.g., MFI and CFI, was studied. Dinuclear iron clusters in appropriate zeolites accomplished oxidation of methane into methanol at room temperature after N2O activation. Both mono and dinuclear iron coordination and lattice coordination was treated with theory and experiment. FeCIT-5 and Fe-ZSM5 were developed by "over-exchange" via sublimation of iron salts in Al-zeolites. When extra-framework iron oxides were made in zeolites, the extra-framework iron oxide clusters can be anchored to zeolites. This is an abstract of a paper presented at the 13th International Zeolite Conference (Montpellier, France 7/8-13/2001).

Original languageEnglish
Title of host publicationZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001
EditorsF. Fajula, F. Di Renzo, A. Galarneau, J. Vedrine
PublisherElsevier Inc.
Pages265
Number of pages1
ISBN (Print)9780444502384
DOIs
Publication statusPublished - 1 Jan 2001
Externally publishedYes
EventZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001 - Montpellier, France
Duration: 8 Jun 200113 Jun 2001

Publication series

NameStudies in Surface Science and Catalysis
Volume135
ISSN (Print)0167-2991

Conference

ConferenceZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001
Country/TerritoryFrance
CityMontpellier
Period8/06/0113/06/01

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