Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

Laurent El Kaim; Cyril Ollivier

doi:10.1055/s-1997-5760

Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

Laurent El Kaim
, Cyril Ollivier

Research output: Contribution to journal › Article › peer-review

Abstract

Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

Original language	English
Pages (from-to)	797-798
Number of pages	2
Journal	Synlett
Volume	1997
Issue number	7
DOIs	https://doi.org/10.1055/s-1997-5760
Publication status	Published - 1 Jan 1997

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title = "Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds",

abstract = "Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.",

author = "\{El Kaim\}, Laurent and Cyril Ollivier",

year = "1997",

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doi = "10.1055/s-1997-5760",

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journal = "Synlett",

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AU - El Kaim, Laurent

AU - Ollivier, Cyril

PY - 1997/1/1

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N2 - Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

AB - Trifluoropyruvamides in their hydrated form readily react with diazo esters affording new trifluoromethyl epoxides. Activating the pyruvamide with trifluoroacetic anhydride leads to a complete change in selectivity with the formation of a new diazo compound.

U2 - 10.1055/s-1997-5760

DO - 10.1055/s-1997-5760

M3 - Article

AN - SCOPUS:0010541713

SN - 0936-5214

VL - 1997

SP - 797

EP - 798

JO - Synlett

JF - Synlett

IS - 7

ER -

Diazo Esters Addition to Trifluoropyruvamides: New Access to Highly Functionalized Trifluoromethyl Epoxides and Diazo Compounds

Abstract

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