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Differences in the interaction of 1,2,3-triphenylphosphirene with platinum(II) and platinum(0) complexes. Crystal and molecular structures of cis-[PtCl2(PPhCPh=CPh)(PEt3)] and cis-[Ptl(PPhMeCPh=CPh) (PPh3)]

  • Salih S. Al-Juaid
  • , Duncan Carmichael
  • , Peter B. Hitchcock
  • , Siegfried Lochschmidt
  • , Angela Marinetti
  • , François Mathey
  • , John F. Nixon
  • University of Sussex
  • CNRS

Research output: Contribution to journalArticlepeer-review

Abstract

1,2,3-Triphenylphosphirene undergoes only η1-co-ordination with PtII complexes whereas with Pt0 centres insertion also occurs to yield phosphaplatinacyclobutene products.

Original languageEnglish
Pages (from-to)1156-1158
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
Publication statusPublished - 1 Jan 1988
Externally publishedYes

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