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Dips and rims in dried colloidal films

  • C. Parneix
  • , P. Vandoolaeghe
  • , V. S. Nikolayev
  • , D. Quéré
  • , J. Li
  • , B. Cabane
  • UMR 7636 CNRS-ESPCI ParisTech-Université Pierre et Marie Curie
  • Univ. Joseph Fourier-Grenoble 1

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

We describe a spatial pattern arising from the nonuniform evaporation of a colloidal film. Immediately after the film deposition, an obstacle is positioned above its free surface, minimizing evaporation at this location. In a first stage, the film dries everywhere but under the obstacle, where a liquid region remains. Subsequently, this liquid region evaporates near its boundaries with the dry film. This loss of water causes a flow of liquid and particles from the center of the obstructed region to its periphery. The final film has a dip surrounded by a rim whose diameter is set by the obstacle. This turns out to be a simple technique for structuring films of nanometric thickness.

Original languageEnglish
Article number266103
JournalPhysical Review Letters
Volume105
Issue number26
DOIs
Publication statusPublished - 29 Dec 2010
Externally publishedYes

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