Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

M. Destarac; D. Charmot; X. Franck; S. Z. Zard

doi:10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5

Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

M. Destarac
, D. Charmot
, X. Franck
, S. Z. Zard

Research output: Contribution to journal › Article › peer-review

Abstract

Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups.

Original language	English
Pages (from-to)	1035-1039
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	21
Issue number	15
DOIs	https://doi.org/10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5
Publication status	Published - 1 Jan 2000

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abstract = "Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups.",

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AB - Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups.

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Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

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