Abstract
Here we report results obtained by neutron spin echo on semidilute theta solutions of polystyrene in deuterated cyclohexane. It is shown that the pertinent length for the diffusion coefficient is not the correlation length ξθ of concentration fluctuations but rather the distance between binary contacts. At length scales smaller than this distance, the dynamics is linked to the local viscosity, which is found to be surprisingly concentration and temperature dependent.
| Original language | English |
|---|---|
| Pages (from-to) | 3673-3676 |
| Number of pages | 4 |
| Journal | Physical Review Letters |
| Volume | 77 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 1 Jan 1996 |
| Externally published | Yes |