Electrical conductivity of FeCl3-doped poly(alkynylsilane)s

Robert J.P. Corriu; William E. Douglas; Zhi Xin Yang; Francis Garnier; Abderahim Yassar

doi:10.1016/0022-328X(91)80205-X

Electrical conductivity of FeCl₃-doped poly(alkynylsilane)s

Robert J.P. Corriu
, William E. Douglas
, Zhi Xin Yang
, Francis Garnier
, Abderahim Yassar

Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

Abstract

The electrical conductivies of the poly(alkynylsilane)s [C-SiR¹R²-CC-Z]_n (R¹R²Si = Ph₂Si, ⁿOct(Me)Si, 2,3.4,5-tetraphenyl-1-sila-2,4-cyclopentene; Z = (hetero)aromatic group) doped with FeCl₃ are found to lie in the range 10^-9 < α < 10^-3 S cm^-1, whereas those of the undoped polymers are less than 10^-10 S cm^-1. The presence of Ph groups on Si leads to incresed conductivity.

Original language	English
Pages (from-to)	C50-C52
Journal	Journal of Organometallic Chemistry
Volume	417
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)80205-X
Publication status	Published - 8 Oct 1991

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@article{a3b10917605446de8c93306f7f9bd7e8,

title = "Electrical conductivity of FeCl3-doped poly(alkynylsilane)s",

abstract = "The electrical conductivies of the poly(alkynylsilane)s [C-SiR1R2-CC-Z]n (R1R2Si = Ph2Si, nOct(Me)Si, 2,3.4,5-tetraphenyl-1-sila-2,4-cyclopentene; Z = (hetero)aromatic group) doped with FeCl3 are found to lie in the range 10-9 < α < 10-3 S cm-1, whereas those of the undoped polymers are less than 10-10 S cm-1. The presence of Ph groups on Si leads to incresed conductivity.",

author = "Corriu, \{Robert J.P.\} and Douglas, \{William E.\} and Yang, \{Zhi Xin\} and Francis Garnier and Abderahim Yassar",

year = "1991",

month = oct,

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doi = "10.1016/0022-328X(91)80205-X",

language = "English",

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journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Electrical conductivity of FeCl3-doped poly(alkynylsilane)s

AU - Corriu, Robert J.P.

AU - Douglas, William E.

AU - Yang, Zhi Xin

AU - Garnier, Francis

AU - Yassar, Abderahim

PY - 1991/10/8

Y1 - 1991/10/8

N2 - The electrical conductivies of the poly(alkynylsilane)s [C-SiR1R2-CC-Z]n (R1R2Si = Ph2Si, nOct(Me)Si, 2,3.4,5-tetraphenyl-1-sila-2,4-cyclopentene; Z = (hetero)aromatic group) doped with FeCl3 are found to lie in the range 10-9 < α < 10-3 S cm-1, whereas those of the undoped polymers are less than 10-10 S cm-1. The presence of Ph groups on Si leads to incresed conductivity.

AB - The electrical conductivies of the poly(alkynylsilane)s [C-SiR1R2-CC-Z]n (R1R2Si = Ph2Si, nOct(Me)Si, 2,3.4,5-tetraphenyl-1-sila-2,4-cyclopentene; Z = (hetero)aromatic group) doped with FeCl3 are found to lie in the range 10-9 < α < 10-3 S cm-1, whereas those of the undoped polymers are less than 10-10 S cm-1. The presence of Ph groups on Si leads to incresed conductivity.

U2 - 10.1016/0022-328X(91)80205-X

DO - 10.1016/0022-328X(91)80205-X

M3 - Article

AN - SCOPUS:0002887260

SN - 0022-328X

VL - 417

SP - C50-C52

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Electrical conductivity of FeCl3-doped poly(alkynylsilane)s

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Electrical conductivity of FeCl₃-doped poly(alkynylsilane)s