Electrochemical aerobic oxidation of aminocyclopropanes to endoperoxides

Claire Madelaine; Yvan Six; Olivier Buriez

doi:10.1002/anie.200702903

Electrochemical aerobic oxidation of aminocyclopropanes to endoperoxides

Claire Madelaine
, Yvan Six
, Olivier Buriez

Centre national de la recherche scientifique
PSL research University & IPSL

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Electrical synthesizer: Results of cyclic voltammetric studies on a range of aminocyclopropanes in the absence or in the presence of oxygen are in full agreement with the currently accepted autocatalytic mechanism for the aerobic oxidation of these compounds. A simple and efficient procedure was developed for the electrosynthesis of the corresponding endoperoxides (see scheme), some of which exhibit moderate antimalarial activity.

Original language	English
Pages (from-to)	8046-8049
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	42
DOIs	https://doi.org/10.1002/anie.200702903
Publication status	Published - 1 Jan 2007

Keywords

Cyclic voltammetry
Electrochemical oxidation
Peroxides
Small ring systems
Titanium

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10.1002/anie.200702903

Cite this

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abstract = "(Chemical Equation Presented) Electrical synthesizer: Results of cyclic voltammetric studies on a range of aminocyclopropanes in the absence or in the presence of oxygen are in full agreement with the currently accepted autocatalytic mechanism for the aerobic oxidation of these compounds. A simple and efficient procedure was developed for the electrosynthesis of the corresponding endoperoxides (see scheme), some of which exhibit moderate antimalarial activity.",

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author = "Claire Madelaine and Yvan Six and Olivier Buriez",

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KW - Cyclic voltammetry

KW - Electrochemical oxidation

KW - Peroxides

KW - Small ring systems

KW - Titanium

UR - https://www.scopus.com/pages/publications/35649020765

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AN - SCOPUS:35649020765

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 42

ER -

Electrochemical aerobic oxidation of aminocyclopropanes to endoperoxides

Abstract

Keywords

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