Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

François Terrier; Sami Lakhdar; Régis Goumont; Taoufik Boubaker; Erwin Buncel

doi:10.1039/b410356d

Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

François Terrier
, Sami Lakhdar
, Régis Goumont
, Taoufik Boubaker
, Erwin Buncel

Université Versailles-Saint Quentin
Faculté des Sciences de Monastir
Department of Chemistry
Queen's University

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related S_NAr substitutions.

Original language	English
Pages (from-to)	2586-2587
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/b410356d
Publication status	Published - 21 Nov 2004
Externally published	Yes

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10.1039/b410356d

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title = "Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures",

abstract = "Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.",

author = "Fran{\c c}ois Terrier and Sami Lakhdar and R{\'e}gis Goumont and Taoufik Boubaker and Erwin Buncel",

year = "2004",

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doi = "10.1039/b410356d",

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T1 - Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

AU - Terrier, François

AU - Lakhdar, Sami

AU - Goumont, Régis

AU - Boubaker, Taoufik

AU - Buncel, Erwin

PY - 2004/11/21

Y1 - 2004/11/21

N2 - Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.

AB - Using appropriate sets of reference nucleophiles, the reactivity of neutral electrophiles of widely different reactivity and structure has been ranked on the comprehensive electrophilicity scale of Mayr (Acc. Chem. Res., 2003, 36, 66), holding promise of a general rationalization of σ-complexation processes and related SNAr substitutions.

UR - https://www.scopus.com/pages/publications/9944236825

U2 - 10.1039/b410356d

DO - 10.1039/b410356d

M3 - Article

AN - SCOPUS:9944236825

SN - 1359-7345

SP - 2586

EP - 2587

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Electrophilicity parameters for σ-complexation by uncharged electron-deficient aromatic and heteroaromatic structures

Abstract

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