Electrosynthesis of 3-thienylzinc bromide from 3-bromothiophene via a nickel catalysis

C. Gosmini; J. Y. Nédélec; J. Périchon

doi:10.1016/S0040-4039(97)00259-1

Electrosynthesis of 3-thienylzinc bromide from 3-bromothiophene via a nickel catalysis

C. Gosmini
, J. Y. Nédélec
, J. Périchon

Institut de Chimie et des Matériaux de Paris Est, CNRS UPEC/UMR 7182

Research output: Contribution to journal › Article › peer-review

Abstract

3-Thienylzinc bromide is prepared under mild conditions by electroreduction of a DMF solution of 3-bromothiophene, zinc bromide, and a catalytic amount of nickel-bipyridine complex using a magnesium rod as sacrificial anode. The resulting organometallic is then coupled with aryl halides using a palladium catalysis.

Original language	English
Pages (from-to)	1941-1942
Number of pages	2
Journal	Tetrahedron Letters
Volume	38
Issue number	11
DOIs	https://doi.org/10.1016/S0040-4039(97)00259-1
Publication status	Published - 17 Mar 1997
Externally published	Yes

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title = "Electrosynthesis of 3-thienylzinc bromide from 3-bromothiophene via a nickel catalysis",

abstract = "3-Thienylzinc bromide is prepared under mild conditions by electroreduction of a DMF solution of 3-bromothiophene, zinc bromide, and a catalytic amount of nickel-bipyridine complex using a magnesium rod as sacrificial anode. The resulting organometallic is then coupled with aryl halides using a palladium catalysis.",

author = "C. Gosmini and N{\'e}d{\'e}lec, \{J. Y.\} and J. P{\'e}richon",

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AU - Gosmini, C.

AU - Nédélec, J. Y.

AU - Périchon, J.

PY - 1997/3/17

Y1 - 1997/3/17

N2 - 3-Thienylzinc bromide is prepared under mild conditions by electroreduction of a DMF solution of 3-bromothiophene, zinc bromide, and a catalytic amount of nickel-bipyridine complex using a magnesium rod as sacrificial anode. The resulting organometallic is then coupled with aryl halides using a palladium catalysis.

AB - 3-Thienylzinc bromide is prepared under mild conditions by electroreduction of a DMF solution of 3-bromothiophene, zinc bromide, and a catalytic amount of nickel-bipyridine complex using a magnesium rod as sacrificial anode. The resulting organometallic is then coupled with aryl halides using a palladium catalysis.

U2 - 10.1016/S0040-4039(97)00259-1

DO - 10.1016/S0040-4039(97)00259-1

M3 - Article

AN - SCOPUS:0031575743

SN - 0040-4039

VL - 38

SP - 1941

EP - 1942

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 11

ER -

Electrosynthesis of 3-thienylzinc bromide from 3-bromothiophene via a nickel catalysis

Abstract

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