EMF measurements and thermodynamic description of the Pb-Sn-Zn liquid phase

N. David; V. Vassiliev; J. Hertz; J. M. Fiorani; M. Vilasi

doi:10.3139/146.017924

EMF measurements and thermodynamic description of the Pb-Sn-Zn liquid phase

N. David
, V. Vassiliev
, J. Hertz
, J. M. Fiorani
, M. Vilasi

Research output: Contribution to journal › Article › peer-review

Abstract

An electrochemical cell *Zn | Zn²⁺ in LiCl, KCl | Pb _xSn_yZn_z has been made to measure the activity of zinc in the liquid phase of the ternary Pb-Sn-Zn and to determine the liquid miscibility gap. In this paper we present an assessment of the ternary Pb-Sn-Zn system. An optimization of the liquid phase based on the description of the Pb-Sn and Sn-Zn systems by Ohtani et al. Lee and our work on Pb-Zn, has been carried out taking into account available thermodynamic and phase diagram data. All ternary phases are described by the Redlich - Kister - Muggianu model. The optimized coefficients obtained and the calculated phase diagram are presented.

Original language	English
Pages (from-to)	124-131
Number of pages	8
Journal	Zeitschrift fuer Metallkunde/Materials Research and Advanced Techniques
Volume	95
Issue number	3
DOIs	https://doi.org/10.3139/146.017924
Publication status	Published - 1 Jan 2004
Externally published	Yes

Keywords

Calphad method
EMF measurement
Modeling
Pb-sn-zn
Thermodynamic

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10.3139/146.017924

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title = "EMF measurements and thermodynamic description of the Pb-Sn-Zn liquid phase",

abstract = "An electrochemical cell *Zn | Zn2+ in LiCl, KCl | Pb xSnyZnz has been made to measure the activity of zinc in the liquid phase of the ternary Pb-Sn-Zn and to determine the liquid miscibility gap. In this paper we present an assessment of the ternary Pb-Sn-Zn system. An optimization of the liquid phase based on the description of the Pb-Sn and Sn-Zn systems by Ohtani et al. Lee and our work on Pb-Zn, has been carried out taking into account available thermodynamic and phase diagram data. All ternary phases are described by the Redlich - Kister - Muggianu model. The optimized coefficients obtained and the calculated phase diagram are presented.",

keywords = "Calphad method, EMF measurement, Modeling, Pb-sn-zn, Thermodynamic",

author = "N. David and V. Vassiliev and J. Hertz and Fiorani, \{J. M.\} and M. Vilasi",

year = "2004",

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doi = "10.3139/146.017924",

language = "English",

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TY - JOUR

T1 - EMF measurements and thermodynamic description of the Pb-Sn-Zn liquid phase

AU - David, N.

AU - Vassiliev, V.

AU - Hertz, J.

AU - Fiorani, J. M.

AU - Vilasi, M.

PY - 2004/1/1

Y1 - 2004/1/1

N2 - An electrochemical cell *Zn | Zn2+ in LiCl, KCl | Pb xSnyZnz has been made to measure the activity of zinc in the liquid phase of the ternary Pb-Sn-Zn and to determine the liquid miscibility gap. In this paper we present an assessment of the ternary Pb-Sn-Zn system. An optimization of the liquid phase based on the description of the Pb-Sn and Sn-Zn systems by Ohtani et al. Lee and our work on Pb-Zn, has been carried out taking into account available thermodynamic and phase diagram data. All ternary phases are described by the Redlich - Kister - Muggianu model. The optimized coefficients obtained and the calculated phase diagram are presented.

AB - An electrochemical cell *Zn | Zn2+ in LiCl, KCl | Pb xSnyZnz has been made to measure the activity of zinc in the liquid phase of the ternary Pb-Sn-Zn and to determine the liquid miscibility gap. In this paper we present an assessment of the ternary Pb-Sn-Zn system. An optimization of the liquid phase based on the description of the Pb-Sn and Sn-Zn systems by Ohtani et al. Lee and our work on Pb-Zn, has been carried out taking into account available thermodynamic and phase diagram data. All ternary phases are described by the Redlich - Kister - Muggianu model. The optimized coefficients obtained and the calculated phase diagram are presented.

KW - Calphad method

KW - EMF measurement

KW - Modeling

KW - Pb-sn-zn

KW - Thermodynamic

UR - https://www.scopus.com/pages/publications/16544375327

U2 - 10.3139/146.017924

DO - 10.3139/146.017924

M3 - Article

AN - SCOPUS:16544375327

SN - 0044-3093

VL - 95

SP - 124

EP - 131

JO - Zeitschrift fuer Metallkunde/Materials Research and Advanced Techniques

JF - Zeitschrift fuer Metallkunde/Materials Research and Advanced Techniques

IS - 3

ER -

EMF measurements and thermodynamic description of the Pb-Sn-Zn liquid phase

Abstract

Keywords

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