Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Manal Diab; Sébastien Floquet; Mohamed Haouas; Pavel A. Abramov; Xavier López; David Landy; Aurélie Damond; Clément Falaise; Vincent Guérineau; David Touboul; Daoud Naoufal; Emmanuel Cadot

doi:10.1002/ejic.201900602

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Manal Diab
, Sébastien Floquet
, Mohamed Haouas
, Pavel A. Abramov
, Xavier López
, David Landy
, Aurélie Damond
, Clément Falaise
, Vincent Guérineau
, David Touboul
, Daoud Naoufal
, Emmanuel Cadot

Research output: Contribution to journal › Article › peer-review

Abstract

This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

Original language	English
Pages (from-to)	3373-3382
Number of pages	10
Journal	European Journal of Inorganic Chemistry
Volume	2019
Issue number	29
DOIs	https://doi.org/10.1002/ejic.201900602
Publication status	Published - 7 Aug 2019
Externally published	Yes

Keywords

Boron
Chaotropes
Cyclodextrins
Host-guest systems
Structure elucidation

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10.1002/ejic.201900602

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Diab, M., Floquet, S., Haouas, M., Abramov, P. A., López, X., Landy, D., Damond, A., Falaise, C., Guérineau, V., Touboul, D., Naoufal, D., & Cadot, E. (2019). Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations. European Journal of Inorganic Chemistry, 2019(29), 3373-3382. https://doi.org/10.1002/ejic.201900602

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title = "Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations",

abstract = "This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.",

keywords = "Boron, Chaotropes, Cyclodextrins, Host-guest systems, Structure elucidation",

author = "Manal Diab and S{\'e}bastien Floquet and Mohamed Haouas and Abramov, \{Pavel A.\} and Xavier L{\'o}pez and David Landy and Aur{\'e}lie Damond and Cl{\'e}ment Falaise and Vincent Gu{\'e}rineau and David Touboul and Daoud Naoufal and Emmanuel Cadot",

note = "Publisher Copyright: {\textcopyright} 2019 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = aug,

day = "7",

doi = "10.1002/ejic.201900602",

language = "English",

volume = "2019",

pages = "3373--3382",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

number = "29",

}

Diab, M, Floquet, S, Haouas, M, Abramov, PA, López, X, Landy, D, Damond, A, Falaise, C, Guérineau, V, Touboul, D, Naoufal, D & Cadot, E 2019, 'Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations', European Journal of Inorganic Chemistry, vol. 2019, no. 29, pp. 3373-3382. https://doi.org/10.1002/ejic.201900602

TY - JOUR

T1 - Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins

T2 - Synthesis, Solution Studies, and DFT Calculations

AU - Diab, Manal

AU - Floquet, Sébastien

AU - Haouas, Mohamed

AU - Abramov, Pavel A.

AU - López, Xavier

AU - Landy, David

AU - Damond, Aurélie

AU - Falaise, Clément

AU - Guérineau, Vincent

AU - Touboul, David

AU - Naoufal, Daoud

AU - Cadot, Emmanuel

PY - 2019/8/7

Y1 - 2019/8/7

N2 - This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

AB - This paper deals with the formation of host-guest systems between cyclodextrins and the closo-decahydrodecaborate cluster. The inclusion processes, although involving weak interaction, were evidenced in solution by ESI-MS and various NMR techniques. ITC measurements provided thermodynamic parameters, and DFT calculations gave some elements that help in understanding these processes.

KW - Boron

KW - Chaotropes

KW - Cyclodextrins

KW - Host-guest systems

KW - Structure elucidation

U2 - 10.1002/ejic.201900602

DO - 10.1002/ejic.201900602

M3 - Article

AN - SCOPUS:85069654268

SN - 1434-1948

VL - 2019

SP - 3373

EP - 3382

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 29

ER -

Encapsulation of Chaotropic closo-Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

Abstract

Keywords

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