Abstract
We propose an efficient numerical approach to simulate the boundary local time of reflected Brownian motion, as well as the time and position of the associated reaction event on a smooth boundary of a Euclidean domain. This approach combines the standard walk-on-spheres algorithm in the bulk with the approximate solution of the escape problem in a boundary layer. In this way, the most time-consuming simulation of multiple reflections on the boundary is replaced by an equivalent escape event. We validate the proposed escape-from-a-layer approach by comparing simulated statistics of the boundary local time with exact results known for simple domains (a disk, a circular annulus, a sphere, a spherical shell) and with the numerical results obtained by a finite-element method in more sophisticated domains. This approach offers a powerful tool for simulating reflected Brownian motion in multi-scale confinements such as porous media or biological environments, and for solving the related partial differential equations. Its applications in the context of diffusion-controlled reactions in chemical physics are discussed.
| Original language | English |
|---|---|
| Article number | 114099 |
| Journal | Journal of Computational Physics |
| Volume | 537 |
| DOIs | |
| Publication status | Published - 15 Sept 2025 |
Keywords
- Boundary local time
- Diffusion-controlled reaction
- Escape problem
- Monte Carlo simulation
- Reflected Brownian motion
- Robin and Neumann boundary conditions
- Walk-on-spheres
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