Evaluation of specific interactions of solid surfaces by inverse gas chromatography - A new approach based on polarizability of the probes

J. B. Donnet; S. J. Park; H. Balard

doi:10.1007/BF02262385

Evaluation of specific interactions of solid surfaces by inverse gas chromatography - A new approach based on polarizability of the probes

J. B. Donnet
, S. J. Park
, H. Balard

Centre national de la recherche scientifique
ENSCMu École Nationale Supérieure de Chimie de Mulhouse

Research output: Contribution to journal › Article › peer-review

209 Citations (Scopus)

Abstract

A method is presented for the determination of London dispersive forces and specific interactions between adsorbate and adsorbent, taking into account the deformation polarizability in inverse gas chromatography (IGC) at infinite dilution. Previous methods for the interpretation of IGC experimental results have frequently revealed their inadequacies and limits in the case of solids such as carbon blacks, graphite powders and carbon fibres, or led to rough estimations when based on molar deformation polarization only.

Original language	English
Pages (from-to)	434-440
Number of pages	7
Journal	Chromatographia
Volume	31
Issue number	9-10
DOIs	https://doi.org/10.1007/BF02262385
Publication status	Published - 1 May 1991
Externally published	Yes

Keywords

Deformation polarizability
Inverse gas chromatography
London dispersive forces and specific interactions
Natural graphite

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10.1007/BF02262385

Cite this

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abstract = "A method is presented for the determination of London dispersive forces and specific interactions between adsorbate and adsorbent, taking into account the deformation polarizability in inverse gas chromatography (IGC) at infinite dilution. Previous methods for the interpretation of IGC experimental results have frequently revealed their inadequacies and limits in the case of solids such as carbon blacks, graphite powders and carbon fibres, or led to rough estimations when based on molar deformation polarization only.",

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AU - Balard, H.

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Y1 - 1991/5/1

N2 - A method is presented for the determination of London dispersive forces and specific interactions between adsorbate and adsorbent, taking into account the deformation polarizability in inverse gas chromatography (IGC) at infinite dilution. Previous methods for the interpretation of IGC experimental results have frequently revealed their inadequacies and limits in the case of solids such as carbon blacks, graphite powders and carbon fibres, or led to rough estimations when based on molar deformation polarization only.

AB - A method is presented for the determination of London dispersive forces and specific interactions between adsorbate and adsorbent, taking into account the deformation polarizability in inverse gas chromatography (IGC) at infinite dilution. Previous methods for the interpretation of IGC experimental results have frequently revealed their inadequacies and limits in the case of solids such as carbon blacks, graphite powders and carbon fibres, or led to rough estimations when based on molar deformation polarization only.

KW - Deformation polarizability

KW - Inverse gas chromatography

KW - London dispersive forces and specific interactions

KW - Natural graphite

UR - https://www.scopus.com/pages/publications/0025774628

U2 - 10.1007/BF02262385

DO - 10.1007/BF02262385

M3 - Article

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SN - 0009-5893

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JO - Chromatographia

JF - Chromatographia

IS - 9-10

ER -

Evaluation of specific interactions of solid surfaces by inverse gas chromatography - A new approach based on polarizability of the probes

Abstract

Keywords

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