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Experimental and theoretical study of line mixing in methane spectra. IV. Influence of the temperature and of the band

  • D. Pieroni
  • , Nguyen-Van-Thanh
  • , C. Brodbeck
  • , J. M. Hartmann
  • , T. Gabard
  • , J. P. Champion
  • , D. Bermejo
  • , J. L. Domenech
  • , C. Claveau
  • , A. Valentin
  • Centre national de la recherche scientifique
  • Centre de Recherches de Climatologie, CNRS UMR 5210, Université de Bourgogne
  • (IEM-CSIC) Serrano 123

Research output: Contribution to journalArticlepeer-review

Abstract

The infrared bands line-mixing effects of methane perturbed by nitrogen were discussed at different pressures. The spectral shapes of the ν2, ν4 and ν3 bands were compared at room temperature while the ν3 region was employed for the investigation of thermal effects. The effects of collisions in the ν4 region's spectra were calculated at the room temperature. The Coriolis coupling between ν2 and ν4 vibrational states resulted in the failure of evolution modeling with increasing pressure of absorption.

Original languageEnglish
Pages (from-to)5776-5783
Number of pages8
JournalJournal of Chemical Physics
Volume113
Issue number14
DOIs
Publication statusPublished - 8 Oct 2000

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