Experimental investigations and thermodynamic description of the PbO-Bi2O3 system

I. Diop; N. David; J. M. Fiorani; R. Podor; M. Vilasi

doi:10.1016/j.jct.2008.10.012

Experimental investigations and thermodynamic description of the PbO-Bi₂O₃ system

I. Diop, N. David, J. M. Fiorani, R. Podor, M. Vilasi

Univ.́ Henri Poincaré

Research output: Contribution to journal › Article › peer-review

Abstract

In the present work, the experimental characterization of the pseudo-binary PbO-Bi₂O₃ cut has been performed by differential thermal analysis (DTA), isothermal annealing, powder X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). A thermodynamic assessment according to the Calphad method was also performed based on the present results as well as previous experimental data using the ThermoCalc software.

Original language	English
Pages (from-to)	420-432
Number of pages	13
Journal	Journal of Chemical Thermodynamics
Volume	41
Issue number	3
DOIs	https://doi.org/10.1016/j.jct.2008.10.012
Publication status	Published - 1 Mar 2009
Externally published	Yes

Keywords

Calphad method
PbO-BiO phase diagram
Spallation target
Thermodynamic assessment

Access to Document

10.1016/j.jct.2008.10.012

Cite this

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title = "Experimental investigations and thermodynamic description of the PbO-Bi2O3 system",

abstract = "In the present work, the experimental characterization of the pseudo-binary PbO-Bi2O3 cut has been performed by differential thermal analysis (DTA), isothermal annealing, powder X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). A thermodynamic assessment according to the Calphad method was also performed based on the present results as well as previous experimental data using the ThermoCalc software.",

keywords = "Calphad method, PbO-BiO phase diagram, Spallation target, Thermodynamic assessment",

author = "I. Diop and N. David and Fiorani, \{J. M.\} and R. Podor and M. Vilasi",

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AU - Diop, I.

AU - David, N.

AU - Fiorani, J. M.

AU - Podor, R.

AU - Vilasi, M.

PY - 2009/3/1

Y1 - 2009/3/1

N2 - In the present work, the experimental characterization of the pseudo-binary PbO-Bi2O3 cut has been performed by differential thermal analysis (DTA), isothermal annealing, powder X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). A thermodynamic assessment according to the Calphad method was also performed based on the present results as well as previous experimental data using the ThermoCalc software.

AB - In the present work, the experimental characterization of the pseudo-binary PbO-Bi2O3 cut has been performed by differential thermal analysis (DTA), isothermal annealing, powder X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). A thermodynamic assessment according to the Calphad method was also performed based on the present results as well as previous experimental data using the ThermoCalc software.

KW - Calphad method

KW - PbO-BiO phase diagram

KW - Spallation target

KW - Thermodynamic assessment

U2 - 10.1016/j.jct.2008.10.012

DO - 10.1016/j.jct.2008.10.012

M3 - Article

AN - SCOPUS:58149196165

SN - 0021-9614

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EP - 432

JO - Journal of Chemical Thermodynamics

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