Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

Kenneth J.H. Young; Jonas Oxgaard; Daniel H. Ess; Steven K. Meier; Timothy Stewart; William A. Goddard; Roy A. Periana

doi:10.1039/b823303a

Experimental realization of catalytic CH₄ hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

Kenneth J.H. Young
, Jonas Oxgaard
, Daniel H. Ess
, Steven K. Meier
, Timothy Stewart
, William A. Goddard
, Roy A. Periana

University of Southern California
California Institute of Technology
Scripps Florida

Research output: Contribution to journal › Article › peer-review

Abstract

A discrete, air, protic, and thermally stable (NNC)Ir(iii) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO₄ and KIO ₃ gives the oxy-ester.

Original language	English
Pages (from-to)	3270-3272
Number of pages	3
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/b823303a
Publication status	Published - 1 Jan 2009
Externally published	Yes

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10.1039/b823303a

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title = "Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability",

abstract = "A discrete, air, protic, and thermally stable (NNC)Ir(iii) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO4 and KIO 3 gives the oxy-ester.",

author = "Young, \{Kenneth J.H.\} and Jonas Oxgaard and Ess, \{Daniel H.\} and Meier, \{Steven K.\} and Timothy Stewart and Goddard, \{William A.\} and Periana, \{Roy A.\}",

year = "2009",

month = jan,

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doi = "10.1039/b823303a",

language = "English",

pages = "3270--3272",

journal = "Chemical Communications",

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TY - JOUR

T1 - Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

AU - Young, Kenneth J.H.

AU - Oxgaard, Jonas

AU - Ess, Daniel H.

AU - Meier, Steven K.

AU - Stewart, Timothy

AU - Goddard, William A.

AU - Periana, Roy A.

PY - 2009/1/1

Y1 - 2009/1/1

N2 - A discrete, air, protic, and thermally stable (NNC)Ir(iii) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO4 and KIO 3 gives the oxy-ester.

AB - A discrete, air, protic, and thermally stable (NNC)Ir(iii) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO4 and KIO 3 gives the oxy-ester.

U2 - 10.1039/b823303a

DO - 10.1039/b823303a

M3 - Article

AN - SCOPUS:66449104116

SN - 1359-7345

SP - 3270

EP - 3272

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Experimental realization of catalytic CH4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability

Abstract

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Experimental realization of catalytic CH₄ hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability