Facile functionalization of a metal carbon bond by O-atom transfer

Brian L. Conley; Somesh K. Ganesh; Jason M. Gonzales; William J. Tenn; Kenneth J.H. Young; Jonas Oxgaard; William A. Goddard; Roy A. Periana

doi:10.1021/ja062417w

Facile functionalization of a metal carbon bond by O-atom transfer

Brian L. Conley
, Somesh K. Ganesh
, Jason M. Gonzales
, William J. Tenn
, Kenneth J.H. Young
, Jonas Oxgaard
, William A. Goddard
, Roy A. Periana

Research output: Contribution to journal › Article › peer-review

Abstract

The facile conversion of M-R to M-OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer-Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.

Original language	English
Pages (from-to)	9018-9019
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	128
Issue number	28
DOIs	https://doi.org/10.1021/ja062417w
Publication status	Published - 19 Jul 2006
Externally published	Yes

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10.1021/ja062417w

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title = "Facile functionalization of a metal carbon bond by O-atom transfer",

abstract = "The facile conversion of M-R to M-OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer-Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.",

author = "Conley, \{Brian L.\} and Ganesh, \{Somesh K.\} and Gonzales, \{Jason M.\} and Tenn, \{William J.\} and Young, \{Kenneth J.H.\} and Jonas Oxgaard and Goddard, \{William A.\} and Periana, \{Roy A.\}",

year = "2006",

month = jul,

day = "19",

doi = "10.1021/ja062417w",

language = "English",

volume = "128",

pages = "9018--9019",

journal = "Journal of the American Chemical Society",

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T1 - Facile functionalization of a metal carbon bond by O-atom transfer

AU - Conley, Brian L.

AU - Ganesh, Somesh K.

AU - Gonzales, Jason M.

AU - Tenn, William J.

AU - Young, Kenneth J.H.

AU - Oxgaard, Jonas

AU - Goddard, William A.

AU - Periana, Roy A.

PY - 2006/7/19

Y1 - 2006/7/19

N2 - The facile conversion of M-R to M-OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer-Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.

AB - The facile conversion of M-R to M-OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a Baeyer-Villiger-type pathway involving a nonredox, electrophilic, O-atom insertion in reactions with non-peroxo O-donors.

UR - https://www.scopus.com/pages/publications/33746095414

U2 - 10.1021/ja062417w

DO - 10.1021/ja062417w

M3 - Article

AN - SCOPUS:33746095414

SN - 0002-7863

VL - 128

SP - 9018

EP - 9019

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

Facile functionalization of a metal carbon bond by O-atom transfer

Abstract

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