First Carbamates Conversion to Amides by Simple Alkyl Group Transfer from Trialkylalanes

Laurent El Kaim; Laurence Grimaud; Anabelle Lee; Yannick Perroux; Cornelia Tirla

doi:10.1021/ol036234f

First Carbamates Conversion to Amides by Simple Alkyl Group Transfer from Trialkylalanes

Laurent El Kaim
, Laurence Grimaud
, Anabelle Lee
, Yannick Perroux
, Cornelia Tirla

Unité Chimie et Procédés

Research output: Contribution to journal › Article › peer-review

Abstract

(Equation presented) N-Monosubstituted carbamates are cleanly converted to amides under treatment with trialkylaluminum. This reaction involves an aluminum-assisted internal delivery of alkyl groups. It can be applied to new and mild protecting group strategies for alcohols.

Original language	English
Pages (from-to)	381-383
Number of pages	3
Journal	Organic Letters
Volume	6
Issue number	3
DOIs	https://doi.org/10.1021/ol036234f
Publication status	Published - 5 Feb 2004
Externally published	Yes

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title = "First Carbamates Conversion to Amides by Simple Alkyl Group Transfer from Trialkylalanes",

abstract = "(Equation presented) N-Monosubstituted carbamates are cleanly converted to amides under treatment with trialkylaluminum. This reaction involves an aluminum-assisted internal delivery of alkyl groups. It can be applied to new and mild protecting group strategies for alcohols.",

author = "\{El Kaim\}, Laurent and Laurence Grimaud and Anabelle Lee and Yannick Perroux and Cornelia Tirla",

year = "2004",

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doi = "10.1021/ol036234f",

language = "English",

volume = "6",

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journal = "Organic Letters",

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publisher = "American Chemical Society",

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T1 - First Carbamates Conversion to Amides by Simple Alkyl Group Transfer from Trialkylalanes

AU - El Kaim, Laurent

AU - Grimaud, Laurence

AU - Lee, Anabelle

AU - Perroux, Yannick

AU - Tirla, Cornelia

PY - 2004/2/5

Y1 - 2004/2/5

N2 - (Equation presented) N-Monosubstituted carbamates are cleanly converted to amides under treatment with trialkylaluminum. This reaction involves an aluminum-assisted internal delivery of alkyl groups. It can be applied to new and mild protecting group strategies for alcohols.

AB - (Equation presented) N-Monosubstituted carbamates are cleanly converted to amides under treatment with trialkylaluminum. This reaction involves an aluminum-assisted internal delivery of alkyl groups. It can be applied to new and mild protecting group strategies for alcohols.

U2 - 10.1021/ol036234f

DO - 10.1021/ol036234f

M3 - Article

AN - SCOPUS:1342285485

SN - 1523-7060

VL - 6

SP - 381

EP - 383

JO - Organic Letters

JF - Organic Letters

IS - 3

ER -

First Carbamates Conversion to Amides by Simple Alkyl Group Transfer from Trialkylalanes

Abstract

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