First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3) 2], (R = But, adamantyl), (M = Pd, Pt).

Rainer Bartsch; Duncan Carmichael; Peter B. Hitchcock; Mohamed F. Meidine; John F. Nixon; Gary J.D. Sillett

doi:10.1039/C39880001615

First examples of η¹-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C₂R₂P₃)(PEt₃) ₂], (R = Bu^t, adamantyl), (M = Pd, Pt).

Rainer Bartsch
, Duncan Carmichael
, Peter B. Hitchcock
, Mohamed F. Meidine
, John F. Nixon
, Gary J.D. Sillett

University of Sussex

Research output: Contribution to journal › Article › peer-review

Abstract

First examples of η¹-ligated 1,2,4- triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.

Original language	English
Pages (from-to)	1615-1617
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39880001615
Publication status	Published - 1 Dec 1988
Externally published	Yes

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Bartsch, R., Carmichael, D., Hitchcock, P. B., Meidine, M. F., Nixon, J. F., & Sillett, G. J. D. (1988). First examples of η¹-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C₂R₂P₃)(PEt₃) ₂], (R = Bu^t, adamantyl), (M = Pd, Pt). Journal of the Chemical Society, Chemical Communications, (24), 1615-1617. https://doi.org/10.1039/C39880001615

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title = "First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3) 2], (R = But, adamantyl), (M = Pd, Pt).",

abstract = "First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.",

author = "Rainer Bartsch and Duncan Carmichael and Hitchcock, \{Peter B.\} and Meidine, \{Mohamed F.\} and Nixon, \{John F.\} and Sillett, \{Gary J.D.\}",

year = "1988",

month = dec,

day = "1",

doi = "10.1039/C39880001615",

language = "English",

pages = "1615--1617",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

number = "24",

}

Bartsch, R, Carmichael, D, Hitchcock, PB, Meidine, MF, Nixon, JF & Sillett, GJD 1988, 'First examples of η¹-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C₂R₂P₃)(PEt₃) ₂], (R = Bu^t, adamantyl), (M = Pd, Pt).', Journal of the Chemical Society, Chemical Communications, no. 24, pp. 1615-1617. https://doi.org/10.1039/C39880001615

First examples of η¹-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C₂R₂P₃)(PEt₃) ₂], (R = Bu^t, adamantyl), (M = Pd, Pt). / Bartsch, Rainer; Carmichael, Duncan; Hitchcock, Peter B. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 01.12.1988, p. 1615-1617.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3) 2], (R = But, adamantyl), (M = Pd, Pt).

AU - Bartsch, Rainer

AU - Carmichael, Duncan

AU - Hitchcock, Peter B.

AU - Meidine, Mohamed F.

AU - Nixon, John F.

AU - Sillett, Gary J.D.

PY - 1988/12/1

Y1 - 1988/12/1

N2 - First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.

AB - First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems are described and structural features and solution fluxional behaviour are discussed.

U2 - 10.1039/C39880001615

DO - 10.1039/C39880001615

M3 - Article

AN - SCOPUS:51149211810

SN - 0022-4936

SP - 1615

EP - 1617

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -

First examples of η1-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C2R2P3)(PEt3) 2], (R = But, adamantyl), (M = Pd, Pt).

Abstract

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First examples of η¹-ligated 1,2,4- triphosphacyclopentadienyl ring systems. Synthesis and fluxional behaviour of trans-[MCl(C₂R₂P₃)(PEt₃) ₂], (R = Bu^t, adamantyl), (M = Pd, Pt).