First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Antoine Buchard; Audrey Auffrant; Louis Ricard; Xavier F. Le Goff; Rachel H. Platel; Charlotte K. Williams; Pascal Le Floch

doi:10.1039/b918971h

First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Antoine Buchard
, Audrey Auffrant
, Louis Ricard
, Xavier F. Le Goff
, Rachel H. Platel
, Charlotte K. Williams
, Pascal Le Floch

CNRS
Imperial College London

Research output: Contribution to journal › Article › peer-review

Abstract

Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.

Original language	English
Pages (from-to)	10219-10222
Number of pages	4
Journal	Dalton Transactions
Issue number	46
DOIs	https://doi.org/10.1039/b918971h
Publication status	Published - 27 Nov 2009
Externally published	Yes

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10.1039/b918971h

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title = "First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands",

abstract = "Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.",

author = "Antoine Buchard and Audrey Auffrant and Louis Ricard and \{Le Goff\}, \{Xavier F.\} and Platel, \{Rachel H.\} and Williams, \{Charlotte K.\} and \{Le Floch\}, Pascal",

year = "2009",

month = nov,

day = "27",

doi = "10.1039/b918971h",

language = "English",

pages = "10219--10222",

journal = "Dalton Transactions",

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T1 - First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

AU - Buchard, Antoine

AU - Auffrant, Audrey

AU - Ricard, Louis

AU - Le Goff, Xavier F.

AU - Platel, Rachel H.

AU - Williams, Charlotte K.

AU - Le Floch, Pascal

PY - 2009/11/27

Y1 - 2009/11/27

N2 - Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.

AB - Serendipitous deprotonation of bis(iminophosphoranyl)methanide Nd(iii) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.

UR - https://www.scopus.com/pages/publications/70450158555

U2 - 10.1039/b918971h

DO - 10.1039/b918971h

M3 - Article

AN - SCOPUS:70450158555

SN - 1477-9226

SP - 10219

EP - 10222

JO - Dalton Transactions

JF - Dalton Transactions

IS - 46

ER -

First neodymium(iii) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Abstract

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