First synthesis of cationic [(η6-arene)Mn(CO)3] complexes substituted by resonance electron withdrawing groups

Audrey Auffrant; Damien Prim; Françoise Rose-Munch; Eric Rose; Jacqueline Vaissermann

doi:10.1021/om010162j

First synthesis of cationic [(η⁶-arene)Mn(CO)₃] complexes substituted by resonance electron withdrawing groups

Audrey Auffrant
, Damien Prim
, Françoise Rose-Munch
, Eric Rose
, Jacqueline Vaissermann

Centre national de la recherche scientifique
E.S.A 8007 du C.N.R.S

Research output: Contribution to journal › Article › peer-review

Abstract

An unprecedented class of cationic [(η⁶-RCO-arene)Mn(CO)₃] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (η⁵-1-chlorocyclohexadienyl)Mn(CO)₃ complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization. Definitive spectroscopic details of the novel [(η⁶-RCO-arene)Mn(CO)₃]⁺ products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography.

Original language	English
Pages (from-to)	3214-3216
Number of pages	3
Journal	Organometallics
Volume	20
Issue number	15
DOIs	https://doi.org/10.1021/om010162j
Publication status	Published - 23 Jul 2001

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title = "First synthesis of cationic [(η6-arene)Mn(CO)3] complexes substituted by resonance electron withdrawing groups",

abstract = "An unprecedented class of cationic [(η6-RCO-arene)Mn(CO)3] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (η5-1-chlorocyclohexadienyl)Mn(CO)3 complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization. Definitive spectroscopic details of the novel [(η6-RCO-arene)Mn(CO)3]+ products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography.",

author = "Audrey Auffrant and Damien Prim and Fran{\c c}oise Rose-Munch and Eric Rose and Jacqueline Vaissermann",

year = "2001",

month = jul,

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doi = "10.1021/om010162j",

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T1 - First synthesis of cationic [(η6-arene)Mn(CO)3] complexes substituted by resonance electron withdrawing groups

AU - Auffrant, Audrey

AU - Prim, Damien

AU - Rose-Munch, Françoise

AU - Rose, Eric

AU - Vaissermann, Jacqueline

PY - 2001/7/23

Y1 - 2001/7/23

N2 - An unprecedented class of cationic [(η6-RCO-arene)Mn(CO)3] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (η5-1-chlorocyclohexadienyl)Mn(CO)3 complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization. Definitive spectroscopic details of the novel [(η6-RCO-arene)Mn(CO)3]+ products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography.

AB - An unprecedented class of cationic [(η6-RCO-arene)Mn(CO)3] complexes bearing resonance electron withdrawing groups have been synthesized by a high-yield two-step methodology starting from the neutral (η5-1-chlorocyclohexadienyl)Mn(CO)3 complex, employing a facile and selective transition-metal-catalyzed carbonylation followed by rearomatization. Definitive spectroscopic details of the novel [(η6-RCO-arene)Mn(CO)3]+ products are discussed, and in one case (R = PhO), the structure has been confirmed by X-ray crystallography.

U2 - 10.1021/om010162j

DO - 10.1021/om010162j

M3 - Article

AN - SCOPUS:0035939684

SN - 0276-7333

VL - 20

SP - 3214

EP - 3216

JO - Organometallics

JF - Organometallics

IS - 15

ER -

First synthesis of cationic [(η6-arene)Mn(CO)3] complexes substituted by resonance electron withdrawing groups

Abstract

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First synthesis of cationic [(η⁶-arene)Mn(CO)₃] complexes substituted by resonance electron withdrawing groups