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Fractal free energy landscapes in structural glasses

  • Duke University
  • Université Paris-Sud
  • PSL research University & IPSL
  • University of Rome
  • Ev-K2-CNR Committee
  • Institut Pierre Simon Laplace, CNRS and CEA

Research output: Contribution to journalArticlepeer-review

399 Citations (Scopus)

Abstract

Glasses are amorphous solids whose constituent particles are caged by their neighbours and thus cannot flow. This sluggishness is often ascribed to the free energy landscape containing multiple minima (basins) separated by high barriers. Here we show, using theory and numerical simulation, that the landscape is much rougher than is classically assumed. Deep in the glass, it undergoes a â roughness transitionâ €™ to fractal basins, which brings about isostaticity and marginal stability on approaching jamming. Critical exponents for the basin width, the weak force distribution and the spatial spread of quasi-contacts near jamming can be analytically determined. Their value is found to be compatible with numerical observations. This advance incorporates the jamming transition of granular materials into the framework of glass theory. Because temperature and pressure control what features of the landscape are experienced, glass mechanics and transport are expected to reflect the features of the topology we discuss here.

Original languageEnglish
Article number3725
JournalNature Communications
Volume5
DOIs
Publication statusPublished - 24 Apr 2014
Externally publishedYes

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