Free-radical variant for the synthesis of functionalized 1,5-diketones

Kelvin Kau Kiat Goh; Sunggak Kim; Samir Z. Zard

doi:10.1021/ol402213k

Free-radical variant for the synthesis of functionalized 1,5-diketones

Kelvin Kau Kiat Goh
, Sunggak Kim
, Samir Z. Zard

Nanyang Technological University
Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

Original language	English
Pages (from-to)	4818-4821
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	18
DOIs	https://doi.org/10.1021/ol402213k
Publication status	Published - 20 Sept 2013
Externally published	Yes

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10.1021/ol402213k

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title = "Free-radical variant for the synthesis of functionalized 1,5-diketones",

abstract = "A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.",

author = "Goh, \{Kelvin Kau Kiat\} and Sunggak Kim and Zard, \{Samir Z.\}",

year = "2013",

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doi = "10.1021/ol402213k",

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pages = "4818--4821",

journal = "Organic Letters",

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AU - Goh, Kelvin Kau Kiat

AU - Kim, Sunggak

AU - Zard, Samir Z.

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Y1 - 2013/9/20

N2 - A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

AB - A free-radical approach for the synthesis of functionalized 1,5-diketones has been accomplished through an effective combination play between alkenylacylphosphonates and keto-xanthates as radical surrogates of enolates and enones, respectively.

U2 - 10.1021/ol402213k

DO - 10.1021/ol402213k

M3 - Article

AN - SCOPUS:84884570126

SN - 1523-7060

VL - 15

SP - 4818

EP - 4821

JO - Organic Letters

JF - Organic Letters

IS - 18

ER -

Free-radical variant for the synthesis of functionalized 1,5-diketones

Abstract

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