Frequency-dependent vibrational population relaxation time of the OH stretching mode in liquid water

G. M. Gale; G. Gallot; N. Lascoux

doi:10.1016/S0009-2614(99)00820-9

Frequency-dependent vibrational population relaxation time of the OH stretching mode in liquid water

G. M. Gale
, G. Gallot
, N. Lascoux

Research output: Contribution to journal › Article › peer-review

Abstract

The vibrational population relaxation time has been measured across the inhomogeneously broadened OH stretching mode (ν₃) of a 0.5% solution of HDO in D₂O. Relaxation times vary from 0.5 ps at low frequency (3270 cm^-1) to 1.0 ps at high frequency (3600 cm^-1). This variation is attributed to a V-V transfer mechanism between ν₃ and 2ν₂.

Original language	English
Pages (from-to)	123-125
Number of pages	3
Journal	Chemical Physics Letters
Volume	311
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(99)00820-9
Publication status	Published - 24 Sept 1999

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@article{645e655a2dc444d4bacc7ad65200e150,

title = "Frequency-dependent vibrational population relaxation time of the OH stretching mode in liquid water",

abstract = "The vibrational population relaxation time has been measured across the inhomogeneously broadened OH stretching mode (ν3) of a 0.5\% solution of HDO in D2O. Relaxation times vary from 0.5 ps at low frequency (3270 cm-1) to 1.0 ps at high frequency (3600 cm-1). This variation is attributed to a V-V transfer mechanism between ν3 and 2ν2.",

author = "Gale, \{G. M.\} and G. Gallot and N. Lascoux",

year = "1999",

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day = "24",

doi = "10.1016/S0009-2614(99)00820-9",

language = "English",

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pages = "123--125",

journal = "Chemical Physics Letters",

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T1 - Frequency-dependent vibrational population relaxation time of the OH stretching mode in liquid water

AU - Gale, G. M.

AU - Gallot, G.

AU - Lascoux, N.

PY - 1999/9/24

Y1 - 1999/9/24

N2 - The vibrational population relaxation time has been measured across the inhomogeneously broadened OH stretching mode (ν3) of a 0.5% solution of HDO in D2O. Relaxation times vary from 0.5 ps at low frequency (3270 cm-1) to 1.0 ps at high frequency (3600 cm-1). This variation is attributed to a V-V transfer mechanism between ν3 and 2ν2.

AB - The vibrational population relaxation time has been measured across the inhomogeneously broadened OH stretching mode (ν3) of a 0.5% solution of HDO in D2O. Relaxation times vary from 0.5 ps at low frequency (3270 cm-1) to 1.0 ps at high frequency (3600 cm-1). This variation is attributed to a V-V transfer mechanism between ν3 and 2ν2.

U2 - 10.1016/S0009-2614(99)00820-9

DO - 10.1016/S0009-2614(99)00820-9

M3 - Article

AN - SCOPUS:0001132124

SN - 0009-2614

VL - 311

SP - 123

EP - 125

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Frequency-dependent vibrational population relaxation time of the OH stretching mode in liquid water

Abstract

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