Frequency-domain two-dimensional infrared spectroscopy using an acousto-optic programmable dispersive filter

We report on multidimensional spectroscopy in the mid-infrared, performed using a calomel-based acousto-optic programmable dispersive filter. Although the associated spectral resolution is currently not as good as what has been previously reported using time-domain interferometers or other pulse-shaping technologies, the extreme compactness of the calomel crystal allows a straightforward implementation in a pre-existing pump-probe setup. Furthermore, the frequency-domain approach allows easy measurement of 2D slices of the multidimensional spectrum associated with a given pump frequency. We demonstrate our method with the measurement of the mid-infrared spectrum of carboxy-hemoglobin in three spectro-temporal dimensions.