From isocyanides to trichloropyruvamides: Application to a new preparation of oxamide derivatives

Laurent El Kaim; Laetitia Gaultier; Laurence Grimaud; Emilie Vieu

doi:10.1016/j.tetlet.2004.08.169

From isocyanides to trichloropyruvamides: Application to a new preparation of oxamide derivatives

Laurent El Kaim
, Laetitia Gaultier
, Laurence Grimaud
, Emilie Vieu

Unité Chimie et Procédés

Research output: Contribution to journal › Article › peer-review

Abstract

Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt ₃ followed by addition of an amine.

Original language	English
Pages (from-to)	8047-8048
Number of pages	2
Journal	Tetrahedron Letters
Volume	45
Issue number	43
DOIs	https://doi.org/10.1016/j.tetlet.2004.08.169
Publication status	Published - 18 Oct 2004
Externally published	Yes

Keywords

Amide
Isocyanides
Pyruvamide
Trichloromethyl

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10.1016/j.tetlet.2004.08.169

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@article{1122ba5179424eb8bc84f3f5bf8ce94e,

title = "From isocyanides to trichloropyruvamides: Application to a new preparation of oxamide derivatives",

abstract = "Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt 3 followed by addition of an amine.",

keywords = "Amide, Isocyanides, Pyruvamide, Trichloromethyl",

author = "\{El Kaim\}, Laurent and Laetitia Gaultier and Laurence Grimaud and Emilie Vieu",

year = "2004",

month = oct,

day = "18",

doi = "10.1016/j.tetlet.2004.08.169",

language = "English",

volume = "45",

pages = "8047--8048",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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}

TY - JOUR

T1 - From isocyanides to trichloropyruvamides

T2 - Application to a new preparation of oxamide derivatives

AU - El Kaim, Laurent

AU - Gaultier, Laetitia

AU - Grimaud, Laurence

AU - Vieu, Emilie

PY - 2004/10/18

Y1 - 2004/10/18

N2 - Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt 3 followed by addition of an amine.

AB - Isocyanides react readily with trichloroacetic acid anhydride forming stable hydrates of trichloropyruvamides. These compounds are valuable intermediates for obtaining oxamides by reaction with TMSCl/NEt 3 followed by addition of an amine.

KW - Amide

KW - Isocyanides

KW - Pyruvamide

KW - Trichloromethyl

U2 - 10.1016/j.tetlet.2004.08.169

DO - 10.1016/j.tetlet.2004.08.169

M3 - Article

AN - SCOPUS:4644220952

SN - 0040-4039

VL - 45

SP - 8047

EP - 8048

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 43

ER -

From isocyanides to trichloropyruvamides: Application to a new preparation of oxamide derivatives

Abstract

Keywords

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