Highly ordered orthorhombic mesoporous silica films

Sophie Besson; Christian Ricolleau; Thierry Gacoin; Catherine Jacquiod; Jean Pierre Boilot

doi:10.1016/S1387-1811(03)00314-7

Highly ordered orthorhombic mesoporous silica films

Sophie Besson
, Christian Ricolleau
, Thierry Gacoin
, Catherine Jacquiod
, Jean Pierre Boilot

Groupe de Chimie du Solide
Laboratoire CNRS/Saint-Gobain
Centre national de la recherche scientifique
Université Pierre et Marie Curie

Research output: Contribution to journal › Article › peer-review

59 Citations (Scopus)

Abstract

Mesoporous silica films are made by the spin-coating technique using an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer (Pluronic PE6800) as template. After optimization of the polymer concentration in the silica sol, films are textured and organized over all the thickness. They exhibit an orthorhombic symmetry (a = 16.0 nm, b = 10.2 nm, c = 23.0 nm) with the b-axis perpendicular to the substrate. This results from a body-centered cubic (bcc) micellar structure which is deformed along the [0 11]_bcc cubic axis, i.e. perpendicular to the film plane.

Original language	English
Pages (from-to)	43-49
Number of pages	7
Journal	Microporous and Mesoporous Materials
Volume	60
Issue number	1-3
DOIs	https://doi.org/10.1016/S1387-1811(03)00314-7
Publication status	Published - 19 Jun 2003

Keywords

Electron microscopy
Mesoporous silica films
Orthorhombic mesoporous structure
Spin-coating on glass
Triblock copolymer

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10.1016/S1387-1811(03)00314-7

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title = "Highly ordered orthorhombic mesoporous silica films",

abstract = "Mesoporous silica films are made by the spin-coating technique using an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer (Pluronic PE6800) as template. After optimization of the polymer concentration in the silica sol, films are textured and organized over all the thickness. They exhibit an orthorhombic symmetry (a = 16.0 nm, b = 10.2 nm, c = 23.0 nm) with the b-axis perpendicular to the substrate. This results from a body-centered cubic (bcc) micellar structure which is deformed along the [0 11]bcc cubic axis, i.e. perpendicular to the film plane.",

keywords = "Electron microscopy, Mesoporous silica films, Orthorhombic mesoporous structure, Spin-coating on glass, Triblock copolymer",

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T1 - Highly ordered orthorhombic mesoporous silica films

AU - Besson, Sophie

AU - Ricolleau, Christian

AU - Gacoin, Thierry

AU - Jacquiod, Catherine

AU - Boilot, Jean Pierre

PY - 2003/6/19

Y1 - 2003/6/19

N2 - Mesoporous silica films are made by the spin-coating technique using an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer (Pluronic PE6800) as template. After optimization of the polymer concentration in the silica sol, films are textured and organized over all the thickness. They exhibit an orthorhombic symmetry (a = 16.0 nm, b = 10.2 nm, c = 23.0 nm) with the b-axis perpendicular to the substrate. This results from a body-centered cubic (bcc) micellar structure which is deformed along the [0 11]bcc cubic axis, i.e. perpendicular to the film plane.

AB - Mesoporous silica films are made by the spin-coating technique using an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer (Pluronic PE6800) as template. After optimization of the polymer concentration in the silica sol, films are textured and organized over all the thickness. They exhibit an orthorhombic symmetry (a = 16.0 nm, b = 10.2 nm, c = 23.0 nm) with the b-axis perpendicular to the substrate. This results from a body-centered cubic (bcc) micellar structure which is deformed along the [0 11]bcc cubic axis, i.e. perpendicular to the film plane.

KW - Electron microscopy

KW - Mesoporous silica films

KW - Orthorhombic mesoporous structure

KW - Spin-coating on glass

KW - Triblock copolymer

U2 - 10.1016/S1387-1811(03)00314-7

DO - 10.1016/S1387-1811(03)00314-7

M3 - Article

AN - SCOPUS:0038817753

SN - 1387-1811

VL - 60

SP - 43

EP - 49

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

IS - 1-3

ER -

Highly ordered orthorhombic mesoporous silica films

Abstract

Keywords

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