How can xanthates control the RAFT polymerization of methacrylates?

Mathias Destarac; Dimitri Matioszek; Xavier Vila; Juliette Ruchmann-Sternchuss; Samir Z. Zard

doi:10.1021/bk-2018-1284.ch013

How can xanthates control the RAFT polymerization of methacrylates?

Mathias Destarac, Dimitri Matioszek, Xavier Vila, Juliette Ruchmann-Sternchuss, Samir Z. Zard

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

A xanthate bearing S-cyanoisopropyl and O-2,2,2-trifluoroethyl groups was identified as a potential RAFT agent for sequential polymerization of methyl methacrylate and vinyl acetate. The intrinsic low reactivity of the xanthate for MMA polymerization was compensated by implementing a semi-batch emulsion process with a thorough adjustment of the process parameters to keep MMA concentration to a minimum during polymerization. In a second stage, the xanthate-capped PMMA seed was chain extended during batch vinyl acetate polymerization at room temperature, yielding a well-defined PMMA-PVAc diblock copolymer.

Original language	English
Title of host publication	Reversible Deactivation Radical Polymerization
Subtitle of host publication	Mechanisms and Synthetic Methodologies
Editors	Nicolay V. Tsarevsky, Haifeng Gao, Krzysztof Matyjaszewski, Brent S. Sumerlin
Publisher	American Chemical Society
Pages	291-305
Number of pages	15
ISBN (Print)	9780841233188
DOIs	https://doi.org/10.1021/bk-2018-1284.ch013
Publication status	Published - 1 Jan 2018
Externally published	Yes

Publication series

Name	ACS Symposium Series
Volume	1284
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

Access to Document

10.1021/bk-2018-1284.ch013

Cite this

Destarac, M., Matioszek, D., Vila, X., Ruchmann-Sternchuss, J., & Zard, S. Z. (2018). How can xanthates control the RAFT polymerization of methacrylates? In N. V. Tsarevsky, H. Gao, K. Matyjaszewski, & B. S. Sumerlin (Eds.), Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies (pp. 291-305). (ACS Symposium Series; Vol. 1284). American Chemical Society. https://doi.org/10.1021/bk-2018-1284.ch013

Destarac, Mathias ; Matioszek, Dimitri ; Vila, Xavier et al. / How can xanthates control the RAFT polymerization of methacrylates?. Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies. editor / Nicolay V. Tsarevsky ; Haifeng Gao ; Krzysztof Matyjaszewski ; Brent S. Sumerlin. American Chemical Society, 2018. pp. 291-305 (ACS Symposium Series).

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title = "How can xanthates control the RAFT polymerization of methacrylates?",

abstract = "A xanthate bearing S-cyanoisopropyl and O-2,2,2-trifluoroethyl groups was identified as a potential RAFT agent for sequential polymerization of methyl methacrylate and vinyl acetate. The intrinsic low reactivity of the xanthate for MMA polymerization was compensated by implementing a semi-batch emulsion process with a thorough adjustment of the process parameters to keep MMA concentration to a minimum during polymerization. In a second stage, the xanthate-capped PMMA seed was chain extended during batch vinyl acetate polymerization at room temperature, yielding a well-defined PMMA-PVAc diblock copolymer.",

author = "Mathias Destarac and Dimitri Matioszek and Xavier Vila and Juliette Ruchmann-Sternchuss and Zard, \{Samir Z.\}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = jan,

day = "1",

doi = "10.1021/bk-2018-1284.ch013",

language = "English",

isbn = "9780841233188",

series = "ACS Symposium Series",

publisher = "American Chemical Society",

pages = "291--305",

editor = "Tsarevsky, \{Nicolay V.\} and Haifeng Gao and Krzysztof Matyjaszewski and Sumerlin, \{Brent S.\}",

booktitle = "Reversible Deactivation Radical Polymerization",

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Destarac, M, Matioszek, D, Vila, X, Ruchmann-Sternchuss, J & Zard, SZ 2018, How can xanthates control the RAFT polymerization of methacrylates? in NV Tsarevsky, H Gao, K Matyjaszewski & BS Sumerlin (eds), Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies. ACS Symposium Series, vol. 1284, American Chemical Society, pp. 291-305. https://doi.org/10.1021/bk-2018-1284.ch013

How can xanthates control the RAFT polymerization of methacrylates? / Destarac, Mathias; Matioszek, Dimitri; Vila, Xavier et al.
Reversible Deactivation Radical Polymerization: Mechanisms and Synthetic Methodologies. ed. / Nicolay V. Tsarevsky; Haifeng Gao; Krzysztof Matyjaszewski; Brent S. Sumerlin. American Chemical Society, 2018. p. 291-305 (ACS Symposium Series; Vol. 1284).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review