Hydrogen plasma treatment of silicon surfaces studied by in-situ spectroscopic ellipsometry

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Abstract

The use of H2 and Ar plasmas for the cleaning of crystalline Si surfaces has been investigated by in-situ spectroscopic ellipsometry (SE), LEED and Auger spectroscopy. H2 plasma treatment, followed by annealing at 700°C to desorb the adsorbed hydrogen, was found to produce high-quality clean crystalline surface. SE was shown to be sensitive not only to surface oxide layers and micro-roughness, but also to monolayer adsorption of hydrogen. The desorption of hydrogen as a function of temperature from H2 plasma treated Si(100) and Si(111) surfaces was investigated. The presence of different phases of adsorbed hydrogen is distinguished by SE, in agreement with UPS and EELS studies. The clean (plasma treated and annealed) Si(100) and Si(111) surfaces show differences in their apparent dielectric constants, which may be due to the nature of the surface reconstruction.

Original languageEnglish
Pages (from-to)435-440
Number of pages6
JournalApplied Surface Science
Volume46
Issue number1-4
DOIs
Publication statusPublished - 2 Dec 1990

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