Abstract
Extraordinarily weak nucleophiles: Enamines derived from imidazolidinones are 10 3-10 5 times less reactive than those derived from the Hayashi-Jørgensen catalyst. This finding explains the lower activity of MacMillan catalysts for enamine-activated reactions.
| Original language | English |
|---|---|
| Pages (from-to) | 5739-5742 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 51 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 4 Jun 2012 |
| Externally published | Yes |
Keywords
- enamines
- kinetics
- linear free energy relationships
- nucleophilicity
- pyramidalization
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