Iminyl Radicals: A Fresh Look at a Forgotten Species (and Some of its Relatives)

Samir Z. Zard

doi:10.1055/s-1996-5698

Iminyl Radicals: A Fresh Look at a Forgotten Species (and Some of its Relatives)

Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

New methods for the generation of iminyl radicals and other related nitrogen centered radicals are described. Intramolecular capture of such species allows an efficient yet simple construction of nitrogen containing heterocycles, especially relevant to the field of alkaloids. Iminyl radicals can also be used to trigger the opening of strained rings such as cyclobutanones and certain cyclopentanones or incorporated in radical cascades in a synthetically useful manner.

Original language	English
Pages (from-to)	1148-1154
Number of pages	7
Journal	Synlett
Volume	1996
Issue number	12
DOIs	https://doi.org/10.1055/s-1996-5698
Publication status	Published - 1 Jan 1996

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abstract = "New methods for the generation of iminyl radicals and other related nitrogen centered radicals are described. Intramolecular capture of such species allows an efficient yet simple construction of nitrogen containing heterocycles, especially relevant to the field of alkaloids. Iminyl radicals can also be used to trigger the opening of strained rings such as cyclobutanones and certain cyclopentanones or incorporated in radical cascades in a synthetically useful manner.",

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N2 - New methods for the generation of iminyl radicals and other related nitrogen centered radicals are described. Intramolecular capture of such species allows an efficient yet simple construction of nitrogen containing heterocycles, especially relevant to the field of alkaloids. Iminyl radicals can also be used to trigger the opening of strained rings such as cyclobutanones and certain cyclopentanones or incorporated in radical cascades in a synthetically useful manner.

AB - New methods for the generation of iminyl radicals and other related nitrogen centered radicals are described. Intramolecular capture of such species allows an efficient yet simple construction of nitrogen containing heterocycles, especially relevant to the field of alkaloids. Iminyl radicals can also be used to trigger the opening of strained rings such as cyclobutanones and certain cyclopentanones or incorporated in radical cascades in a synthetically useful manner.

UR - https://www.scopus.com/pages/publications/0003168906

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DO - 10.1055/s-1996-5698

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Iminyl Radicals: A Fresh Look at a Forgotten Species (and Some of its Relatives)

Abstract

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