Influence of clay addition on ion conductivity of polymeric electrolyte composites

S. Kim; J. Y. Kang; S. G. Lee; J. R. Lee; S. J. Park

doi:10.4028/3-908451-18-3.155

Influence of clay addition on ion conductivity of polymeric electrolyte composites

S. Kim
, J. Y. Kang
, S. G. Lee
, J. R. Lee
, S. J. Park

Advanced Materials Division
Center for Convergent Research of Emerging Virus Infection

Research output: Contribution to journal › Conference article › peer-review

Abstract

In this work, the polymeric electrolyte composites (PECs) based on poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, and lithium montmorillonite (Li-MMT) clay were fabricated, and investigated for understanding the effects of Li-MMT/EC in the polymer matrix on the ionic conductivity. For a lithium battery application, the native sodium cations in MMT were exchanged for lithium cations. As a result, the lithium ion was intercalated into the layer of the MMT clay, and thus PEO entered the galleries of MMT clay. The ionic conductivity was enhanced with increasing MMT contents due to the immobile MMT clay serving as the anion species and the decreased crystallinity of PEO.

Original language	English
Pages (from-to)	155-158
Number of pages	4
Journal	Solid State Phenomena
Volume	111
DOIs	https://doi.org/10.4028/3-908451-18-3.155
Publication status	Published - 1 Jan 2006
Externally published	Yes
Event	Symposium S Science and Technology of Hybrid Materials - ICMAT 2005: 3rd International Conference on Materials for Advanced Technologies; IUMRS-ICAM 2005: International Union of Materials Research Societies-9th International Conference on Advanced M - Singapore, Singapore Duration: 3 Jul 2005 → 8 Jul 2005

Keywords

Crystalline structure
Ionic conductivity
Lithium montmorillonite
Poly(ethylene oxide)
Polymeric electrolyte composites

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10.4028/3-908451-18-3.155

Cite this

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title = "Influence of clay addition on ion conductivity of polymeric electrolyte composites",

abstract = "In this work, the polymeric electrolyte composites (PECs) based on poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, and lithium montmorillonite (Li-MMT) clay were fabricated, and investigated for understanding the effects of Li-MMT/EC in the polymer matrix on the ionic conductivity. For a lithium battery application, the native sodium cations in MMT were exchanged for lithium cations. As a result, the lithium ion was intercalated into the layer of the MMT clay, and thus PEO entered the galleries of MMT clay. The ionic conductivity was enhanced with increasing MMT contents due to the immobile MMT clay serving as the anion species and the decreased crystallinity of PEO.",

keywords = "Crystalline structure, Ionic conductivity, Lithium montmorillonite, Poly(ethylene oxide), Polymeric electrolyte composites",

author = "S. Kim and Kang, \{J. Y.\} and Lee, \{S. G.\} and Lee, \{J. R.\} and Park, \{S. J.\}",

year = "2006",

month = jan,

day = "1",

doi = "10.4028/3-908451-18-3.155",

language = "English",

volume = "111",

pages = "155--158",

journal = "Solid State Phenomena",

issn = "1012-0394",

publisher = "Trans Tech Publications Ltd",

note = "Symposium S Science and Technology of Hybrid Materials - ICMAT 2005: 3rd International Conference on Materials for Advanced Technologies; IUMRS-ICAM 2005: International Union of Materials Research Societies-9th International Conference on Advanced M ; Conference date: 03-07-2005 Through 08-07-2005",

}

TY - JOUR

T1 - Influence of clay addition on ion conductivity of polymeric electrolyte composites

AU - Kim, S.

AU - Kang, J. Y.

AU - Lee, S. G.

AU - Lee, J. R.

AU - Park, S. J.

PY - 2006/1/1

Y1 - 2006/1/1

N2 - In this work, the polymeric electrolyte composites (PECs) based on poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, and lithium montmorillonite (Li-MMT) clay were fabricated, and investigated for understanding the effects of Li-MMT/EC in the polymer matrix on the ionic conductivity. For a lithium battery application, the native sodium cations in MMT were exchanged for lithium cations. As a result, the lithium ion was intercalated into the layer of the MMT clay, and thus PEO entered the galleries of MMT clay. The ionic conductivity was enhanced with increasing MMT contents due to the immobile MMT clay serving as the anion species and the decreased crystallinity of PEO.

AB - In this work, the polymeric electrolyte composites (PECs) based on poly(ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, and lithium montmorillonite (Li-MMT) clay were fabricated, and investigated for understanding the effects of Li-MMT/EC in the polymer matrix on the ionic conductivity. For a lithium battery application, the native sodium cations in MMT were exchanged for lithium cations. As a result, the lithium ion was intercalated into the layer of the MMT clay, and thus PEO entered the galleries of MMT clay. The ionic conductivity was enhanced with increasing MMT contents due to the immobile MMT clay serving as the anion species and the decreased crystallinity of PEO.

KW - Crystalline structure

KW - Ionic conductivity

KW - Lithium montmorillonite

KW - Poly(ethylene oxide)

KW - Polymeric electrolyte composites

UR - https://www.scopus.com/pages/publications/35148883129

U2 - 10.4028/3-908451-18-3.155

DO - 10.4028/3-908451-18-3.155

M3 - Conference article

AN - SCOPUS:35148883129

SN - 1012-0394

VL - 111

SP - 155

EP - 158

JO - Solid State Phenomena

JF - Solid State Phenomena

T2 - Symposium S Science and Technology of Hybrid Materials - ICMAT 2005: 3rd International Conference on Materials for Advanced Technologies; IUMRS-ICAM 2005: International Union of Materials Research Societies-9th International Conference on Advanced M

Y2 - 3 July 2005 through 8 July 2005

ER -

Influence of clay addition on ion conductivity of polymeric electrolyte composites

Abstract

Keywords

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