Influence of line mixing on absorption by CO₂ Q branches in atmospheric balloon-borne spectra near 13 μm

Line mixing in CO₂ Q branches is studied in the 13.2 μm region from balloon-borne atmospheric transmission measurements. Eighty-five spectra were recorded (at 67°N, 22°E) in the 660-960 cm^-1 region using a Fourier transform spectrometer with an unapodized resolution (full width at half maximum) of 0.013 cm^-1. They involve balloon altitudes and tangent heights from 13 to 30 km and a large range of optical thicknesses. The results of computations assuming Voigt line shapes as well as accounting for line mixing are compared with measured transmissions in three CO₂ Q branches of different intensities and symmetries. They confirm the significant effect of line mixing and validate recent line coupling models. As a consequence of the accuracy of the forward approach the Q branches can be used for remote sensing; this should lead to improved precision of pressure/temperature retrievals since absorption in the Q branch wing region is particularly pressure sensitive.