Influence of the surface ligands on the optical and electrical properties of PbS QD solids

Mariya A. Zvaigzne; Alexey E. Aleksandrov; Yaroslav Goltyapin; Alexey R. Tameev; Alexander A. Chistyakov

doi:10.1117/12.2306912

Influence of the surface ligands on the optical and electrical properties of PbS QD solids

Mariya A. Zvaigzne, Alexey E. Aleksandrov, Yaroslav Goltyapin, Alexey R. Tameev, Alexander A. Chistyakov

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

We studied the influence of the ligands on the optical properties of PbS QD solids using the photoluminescence spectra and the kinetics of photoluminescence decay. As the ligand molecule length decreases, the photoluminescence decay becomes faster, which in a good agreement with the theory of the hopping mechanism of charge transfer in QD solids. We also fabricate photovoltaic structures (ITO/PEDOT:PSS/PbS/ZnO/Al) based on PbS QD solids and investigate the influence of various organic ligand molecules on its photovoltaic characteristics. The maximum efficiency was observed in samples with a ligand of intermediate length.

Original language	English
Title of host publication	Nanophotonics VII
Editors	David L. Andrews, Andreas Ostendorf, Angus J. Bain, Jean-Michel Nunzi
Publisher	SPIE
ISBN (Electronic)	9781510618701
DOIs	https://doi.org/10.1117/12.2306912
Publication status	Published - 1 Jan 2018
Externally published	Yes
Event	Nanophotonics VII 2018 - Strasbourg, France Duration: 22 Apr 2018 → 26 Apr 2018

Publication series

Name	Proceedings of SPIE - The International Society for Optical Engineering
Volume	10672
ISSN (Print)	0277-786X
ISSN (Electronic)	1996-756X

Conference

Conference	Nanophotonics VII 2018
Country/Territory	France
City	Strasbourg
Period	22/04/18 → 26/04/18

Keywords

charge transfer
energy transfer
ligands
photovoltaic
quantum dots

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1117/12.2306912

Cite this

Zvaigzne, M. A., Aleksandrov, A. E., Goltyapin, Y., Tameev, A. R., & Chistyakov, A. A. (2018). Influence of the surface ligands on the optical and electrical properties of PbS QD solids. In D. L. Andrews, A. Ostendorf, A. J. Bain, & J.-M. Nunzi (Eds.), Nanophotonics VII Article 1067235 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 10672). SPIE. https://doi.org/10.1117/12.2306912

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title = "Influence of the surface ligands on the optical and electrical properties of PbS QD solids",

abstract = "We studied the influence of the ligands on the optical properties of PbS QD solids using the photoluminescence spectra and the kinetics of photoluminescence decay. As the ligand molecule length decreases, the photoluminescence decay becomes faster, which in a good agreement with the theory of the hopping mechanism of charge transfer in QD solids. We also fabricate photovoltaic structures (ITO/PEDOT:PSS/PbS/ZnO/Al) based on PbS QD solids and investigate the influence of various organic ligand molecules on its photovoltaic characteristics. The maximum efficiency was observed in samples with a ligand of intermediate length.",

keywords = "charge transfer, energy transfer, ligands, photovoltaic, quantum dots",

author = "Zvaigzne, \{Mariya A.\} and Aleksandrov, \{Alexey E.\} and Yaroslav Goltyapin and Tameev, \{Alexey R.\} and Chistyakov, \{Alexander A.\}",

note = "Publisher Copyright: {\textcopyright} COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.; Nanophotonics VII 2018 ; Conference date: 22-04-2018 Through 26-04-2018",

year = "2018",

month = jan,

day = "1",

doi = "10.1117/12.2306912",

language = "English",

series = "Proceedings of SPIE - The International Society for Optical Engineering",

publisher = "SPIE",

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booktitle = "Nanophotonics VII",

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Zvaigzne, MA, Aleksandrov, AE, Goltyapin, Y, Tameev, AR & Chistyakov, AA 2018, Influence of the surface ligands on the optical and electrical properties of PbS QD solids. in DL Andrews, A Ostendorf, AJ Bain & J-M Nunzi (eds), Nanophotonics VII., 1067235, Proceedings of SPIE - The International Society for Optical Engineering, vol. 10672, SPIE, Nanophotonics VII 2018, Strasbourg, France, 22/04/18. https://doi.org/10.1117/12.2306912

Influence of the surface ligands on the optical and electrical properties of PbS QD solids. / Zvaigzne, Mariya A.; Aleksandrov, Alexey E.; Goltyapin, Yaroslav et al.
Nanophotonics VII. ed. / David L. Andrews; Andreas Ostendorf; Angus J. Bain; Jean-Michel Nunzi. SPIE, 2018. 1067235 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 10672).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Influence of the surface ligands on the optical and electrical properties of PbS QD solids

AU - Zvaigzne, Mariya A.

AU - Aleksandrov, Alexey E.

AU - Goltyapin, Yaroslav

AU - Tameev, Alexey R.

AU - Chistyakov, Alexander A.

N1 - Publisher Copyright: © COPYRIGHT SPIE. Downloading of the abstract is permitted for personal use only.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - We studied the influence of the ligands on the optical properties of PbS QD solids using the photoluminescence spectra and the kinetics of photoluminescence decay. As the ligand molecule length decreases, the photoluminescence decay becomes faster, which in a good agreement with the theory of the hopping mechanism of charge transfer in QD solids. We also fabricate photovoltaic structures (ITO/PEDOT:PSS/PbS/ZnO/Al) based on PbS QD solids and investigate the influence of various organic ligand molecules on its photovoltaic characteristics. The maximum efficiency was observed in samples with a ligand of intermediate length.

AB - We studied the influence of the ligands on the optical properties of PbS QD solids using the photoluminescence spectra and the kinetics of photoluminescence decay. As the ligand molecule length decreases, the photoluminescence decay becomes faster, which in a good agreement with the theory of the hopping mechanism of charge transfer in QD solids. We also fabricate photovoltaic structures (ITO/PEDOT:PSS/PbS/ZnO/Al) based on PbS QD solids and investigate the influence of various organic ligand molecules on its photovoltaic characteristics. The maximum efficiency was observed in samples with a ligand of intermediate length.

KW - charge transfer

KW - energy transfer

KW - ligands

KW - photovoltaic

KW - quantum dots

UR - https://www.scopus.com/pages/publications/85049882261

U2 - 10.1117/12.2306912

DO - 10.1117/12.2306912

M3 - Conference contribution

AN - SCOPUS:85049882261

T3 - Proceedings of SPIE - The International Society for Optical Engineering

BT - Nanophotonics VII

A2 - Andrews, David L.

A2 - Ostendorf, Andreas

A2 - Bain, Angus J.

A2 - Nunzi, Jean-Michel

PB - SPIE

T2 - Nanophotonics VII 2018

Y2 - 22 April 2018 through 26 April 2018

ER -

Influence of the surface ligands on the optical and electrical properties of PbS QD solids

Abstract

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Keywords

UN SDGs

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