Insertion reactions of the [RhCl(PPh3)2] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh 3)2], [RhCl(PPhCPh=CPhCO)(PPh3)2] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh3)} 2]

Florence A. Ajulu; Duncan Carmichael; Peter B. Hitchcock; François Mathey; Mohamed F. Meidine; John F. Nixon; Louis Ricard; M. Louise Riley

doi:10.1039/C39920000750

Insertion reactions of the [RhCl(PPh₃)₂] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh ₃)₂], [RhCl(PPhCPh=CPhCO)(PPh₃)₂] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh₃)} ₂]

Florence A. Ajulu
, Duncan Carmichael
, Peter B. Hitchcock
, François Mathey
, Mohamed F. Meidine
, John F. Nixon
, Louis Ricard
, M. Louise Riley

Research output: Contribution to journal › Article › peer-review

Abstract

The first example of insertion of the d⁸ Rh^I fragment [RhCl(PPh₃)₂] into a phosphirene ring system results in a five-coordinate Rh^III complex, which undergoes insertion of carbon monoxide to give either monomeric [RhCl(PPhCPh=CPhCO)(PPh₃) ₂] or dimeric [RhCl(PPhCPh=)(PPh₃)}₂], the structures of which have been elucidated by NMR spectroscopy and single-crystal X-ray diffraction studies.

Original language	English
Pages (from-to)	750-752
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39920000750
Publication status	Published - 1 Dec 1992
Externally published	Yes

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Ajulu, F. A., Carmichael, D., Hitchcock, P. B., Mathey, F., Meidine, M. F., Nixon, J. F., Ricard, L., & Riley, M. L. (1992). Insertion reactions of the [RhCl(PPh₃)₂] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh ₃)₂], [RhCl(PPhCPh=CPhCO)(PPh₃)₂] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh₃)} ₂]. Journal of the Chemical Society, Chemical Communications, (10), 750-752. https://doi.org/10.1039/C39920000750

Ajulu, Florence A. ; Carmichael, Duncan ; Hitchcock, Peter B. et al. / Insertion reactions of the [RhCl(PPh₃)₂] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh ₃)₂], [RhCl(PPhCPh=CPhCO)(PPh₃)₂] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh₃)} ₂]. In: Journal of the Chemical Society, Chemical Communications. 1992 ; No. 10. pp. 750-752.

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title = "Insertion reactions of the [RhCl(PPh3)2] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh 3)2], [RhCl(PPhCPh=CPhCO)(PPh3)2] and the novel dimeric complex [\{RhCl(PPhCPh=CPhCO)(PPh3)\} 2]",

abstract = "The first example of insertion of the d8 RhI fragment [RhCl(PPh3)2] into a phosphirene ring system results in a five-coordinate RhIII complex, which undergoes insertion of carbon monoxide to give either monomeric [RhCl(PPhCPh=CPhCO)(PPh3) 2] or dimeric [RhCl(PPhCPh=)(PPh3)\}2], the structures of which have been elucidated by NMR spectroscopy and single-crystal X-ray diffraction studies.",

author = "Ajulu, \{Florence A.\} and Duncan Carmichael and Hitchcock, \{Peter B.\} and Fran{\c c}ois Mathey and Meidine, \{Mohamed F.\} and Nixon, \{John F.\} and Louis Ricard and Riley, \{M. Louise\}",

year = "1992",

month = dec,

day = "1",

doi = "10.1039/C39920000750",

language = "English",

pages = "750--752",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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Ajulu, FA, Carmichael, D, Hitchcock, PB, Mathey, F, Meidine, MF, Nixon, JF, Ricard, L & Riley, ML 1992, 'Insertion reactions of the [RhCl(PPh₃)₂] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh ₃)₂], [RhCl(PPhCPh=CPhCO)(PPh₃)₂] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh₃)} ₂]', Journal of the Chemical Society, Chemical Communications, no. 10, pp. 750-752. https://doi.org/10.1039/C39920000750

Insertion reactions of the [RhCl(PPh₃)₂] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh ₃)₂], [RhCl(PPhCPh=CPhCO)(PPh₃)₂] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh₃)} ₂]. / Ajulu, Florence A.; Carmichael, Duncan; Hitchcock, Peter B. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 10, 01.12.1992, p. 750-752.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Insertion reactions of the [RhCl(PPh3)2] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh 3)2], [RhCl(PPhCPh=CPhCO)(PPh3)2] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh3)} 2]

AU - Ajulu, Florence A.

AU - Carmichael, Duncan

AU - Hitchcock, Peter B.

AU - Mathey, François

AU - Meidine, Mohamed F.

AU - Nixon, John F.

AU - Ricard, Louis

AU - Riley, M. Louise

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The first example of insertion of the d8 RhI fragment [RhCl(PPh3)2] into a phosphirene ring system results in a five-coordinate RhIII complex, which undergoes insertion of carbon monoxide to give either monomeric [RhCl(PPhCPh=CPhCO)(PPh3) 2] or dimeric [RhCl(PPhCPh=)(PPh3)}2], the structures of which have been elucidated by NMR spectroscopy and single-crystal X-ray diffraction studies.

AB - The first example of insertion of the d8 RhI fragment [RhCl(PPh3)2] into a phosphirene ring system results in a five-coordinate RhIII complex, which undergoes insertion of carbon monoxide to give either monomeric [RhCl(PPhCPh=CPhCO)(PPh3) 2] or dimeric [RhCl(PPhCPh=)(PPh3)}2], the structures of which have been elucidated by NMR spectroscopy and single-crystal X-ray diffraction studies.

U2 - 10.1039/C39920000750

DO - 10.1039/C39920000750

M3 - Article

AN - SCOPUS:37049075976

SN - 0022-4936

SP - 750

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

Ajulu FA, Carmichael D, Hitchcock PB, Mathey F, Meidine MF, Nixon JF et al. Insertion reactions of the [RhCl(PPh₃)₂] fragment into a phosphirene ring, and carbonylation of the resulting rhodium(III) complex. Crystal and molecular structures of [RhCl(PPhCPh=CPh)(PPh ₃)₂], [RhCl(PPhCPh=CPhCO)(PPh₃)₂] and the novel dimeric complex [{RhCl(PPhCPh=CPhCO)(PPh₃)} ₂]. Journal of the Chemical Society, Chemical Communications. 1992 Dec 1;(10):750-752. doi: 10.1039/C39920000750