Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

Grégori Binot; Samir Z. Zard

doi:10.1016/j.tetlet.2003.09.042

Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

Grégori Binot
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

α-Xanthyl cyclobutanones undergo intermolecular radical additions to olefins bearing various functional groups. Adducts containing a phosphonate can be made to cyclise by an internal Wittig-Horner-Emmons reaction to give cyclohexene and cycloheptene rings fused to the cyclobutane.

Original language	English
Pages (from-to)	7703-7706
Number of pages	4
Journal	Tetrahedron Letters
Volume	44
Issue number	42
DOIs	https://doi.org/10.1016/j.tetlet.2003.09.042
Publication status	Published - 13 Oct 2003
Externally published	Yes

Keywords

Cyclobutanones
Intramolecular Horner-Emmons reaction
Radical additions
Xanthate transfer

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10.1016/j.tetlet.2003.09.042

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title = "Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures",

abstract = "α-Xanthyl cyclobutanones undergo intermolecular radical additions to olefins bearing various functional groups. Adducts containing a phosphonate can be made to cyclise by an internal Wittig-Horner-Emmons reaction to give cyclohexene and cycloheptene rings fused to the cyclobutane.",

keywords = "Cyclobutanones, Intramolecular Horner-Emmons reaction, Radical additions, Xanthate transfer",

author = "Gr{\'e}gori Binot and Zard, \{Samir Z.\}",

year = "2003",

month = oct,

day = "13",

doi = "10.1016/j.tetlet.2003.09.042",

language = "English",

volume = "44",

pages = "7703--7706",

journal = "Tetrahedron Letters",

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AU - Binot, Grégori

AU - Zard, Samir Z.

PY - 2003/10/13

Y1 - 2003/10/13

N2 - α-Xanthyl cyclobutanones undergo intermolecular radical additions to olefins bearing various functional groups. Adducts containing a phosphonate can be made to cyclise by an internal Wittig-Horner-Emmons reaction to give cyclohexene and cycloheptene rings fused to the cyclobutane.

AB - α-Xanthyl cyclobutanones undergo intermolecular radical additions to olefins bearing various functional groups. Adducts containing a phosphonate can be made to cyclise by an internal Wittig-Horner-Emmons reaction to give cyclohexene and cycloheptene rings fused to the cyclobutane.

KW - Cyclobutanones

KW - Intramolecular Horner-Emmons reaction

KW - Radical additions

KW - Xanthate transfer

UR - https://www.scopus.com/pages/publications/0141794089

U2 - 10.1016/j.tetlet.2003.09.042

DO - 10.1016/j.tetlet.2003.09.042

M3 - Article

AN - SCOPUS:0141794089

SN - 0040-4039

VL - 44

SP - 7703

EP - 7706

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 42

ER -

Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

Abstract

Keywords

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