Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones

Alexandre Picot; Hellen Dyer; Antoine Buchard; Audrey Auffrant; Laure Vendier; Pascal Le Floch; Sylviane Sabo-Etienne

doi:10.1021/ic902339j

Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones

Alexandre Picot
, Hellen Dyer
, Antoine Buchard
, Audrey Auffrant
, Laure Vendier
, Pascal Le Floch
, Sylviane Sabo-Etienne

CNRS UPR 8241
Université Paul Sabatier
Laboratoire Hétéroéléments et Coordination
CNRS

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H₂)(H₂NNPP)(PCy₃)][BArf₄] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.

Original language	English
Pages (from-to)	1310-1312
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	4
DOIs	https://doi.org/10.1021/ic902339j
Publication status	Published - 15 Feb 2010
Externally published	Yes

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title = "Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones",

abstract = "This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H2)(H2NNPP)(PCy3)][BArf4] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.",

author = "Alexandre Picot and Hellen Dyer and Antoine Buchard and Audrey Auffrant and Laure Vendier and Floch, \{Pascal Le\} and Sylviane Sabo-Etienne",

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T1 - Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones

AU - Picot, Alexandre

AU - Dyer, Hellen

AU - Buchard, Antoine

AU - Auffrant, Audrey

AU - Vendier, Laure

AU - Floch, Pascal Le

AU - Sabo-Etienne, Sylviane

PY - 2010/2/15

Y1 - 2010/2/15

N2 - This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H2)(H2NNPP)(PCy3)][BArf4] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.

AB - This work describes the synthesis of three key intermediates of Noyori-type catalytic systems that are active precatalysts for the transfer hydrogenation of acetophenone. Isolation of the cationic chloro(dihydrogen) complex [RuCl(H2)(H2NNPP)(PCy3)][BArf4] provides a facile synthetic route to the corresponding cationic and neutral hydrido complexes, and the series highlights the links between hydride/dihydrogen and amine/amido ligands in neutral and cationic species.

U2 - 10.1021/ic902339j

DO - 10.1021/ic902339j

M3 - Article

AN - SCOPUS:77249153256

SN - 0020-1669

VL - 49

SP - 1310

EP - 1312

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Interplay between hydrido/dihydrogen and amine/amido ligands in ruthenium-catalyzed transfer hydrogenation of ketones

Abstract

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