J-aggregated dye-MnPS3 hybrid nanoparticles with giant quadratic optical nonlinearity

Too Yi; René Clément; Christian Haut; Laure Catala; Thierry Gacoin; Nicolas Tancrez; Isabelle Ledoux; Joseph Zyss

doi:10.1002/adma.200400583

J-aggregated dye-MnPS₃ hybrid nanoparticles with giant quadratic optical nonlinearity

Too Yi, René Clément, Christian Haut, Laure Catala, Thierry Gacoin, Nicolas Tancrez, Isabelle Ledoux, Joseph Zyss

Research output: Contribution to journal › Article › peer-review

Abstract

An entirely different approach for synthesizing nanoparticles exhibiting giant 'molecular' hyperpolarizability (β) values, evidenced by the spontaneous alignment of several hundreds of dipolar chromophores in each particles, was designed. The strategy to engineer these supramolecular assemblies of nonlinear optics (NLO)-phores involves a combination of several areas of chemistry such as J-aggregates of organic dyes, intercalation in layered materials and control of nanoparticle growth. The β measurements of the [MnPS₃/DAZOP] nanoparticles and of pure DAZOP iodide were performed by harmonic light scattering at 1.91 μm. The nanoparticles and pure DAZOP iodide were dissolved in chloroform in the presence of PVP.

Original language	English
Pages (from-to)	335-338
Number of pages	4
Journal	Advanced Materials
Volume	17
Issue number	3
DOIs	https://doi.org/10.1002/adma.200400583
Publication status	Published - 10 Feb 2005

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10.1002/adma.200400583

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title = "J-aggregated dye-MnPS3 hybrid nanoparticles with giant quadratic optical nonlinearity",

abstract = "An entirely different approach for synthesizing nanoparticles exhibiting giant 'molecular' hyperpolarizability (β) values, evidenced by the spontaneous alignment of several hundreds of dipolar chromophores in each particles, was designed. The strategy to engineer these supramolecular assemblies of nonlinear optics (NLO)-phores involves a combination of several areas of chemistry such as J-aggregates of organic dyes, intercalation in layered materials and control of nanoparticle growth. The β measurements of the [MnPS3/DAZOP] nanoparticles and of pure DAZOP iodide were performed by harmonic light scattering at 1.91 μm. The nanoparticles and pure DAZOP iodide were dissolved in chloroform in the presence of PVP.",

author = "Too Yi and Ren{\'e} Cl{\'e}ment and Christian Haut and Laure Catala and Thierry Gacoin and Nicolas Tancrez and Isabelle Ledoux and Joseph Zyss",

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T1 - J-aggregated dye-MnPS3 hybrid nanoparticles with giant quadratic optical nonlinearity

AU - Yi, Too

AU - Clément, René

AU - Haut, Christian

AU - Catala, Laure

AU - Gacoin, Thierry

AU - Tancrez, Nicolas

AU - Ledoux, Isabelle

AU - Zyss, Joseph

PY - 2005/2/10

Y1 - 2005/2/10

N2 - An entirely different approach for synthesizing nanoparticles exhibiting giant 'molecular' hyperpolarizability (β) values, evidenced by the spontaneous alignment of several hundreds of dipolar chromophores in each particles, was designed. The strategy to engineer these supramolecular assemblies of nonlinear optics (NLO)-phores involves a combination of several areas of chemistry such as J-aggregates of organic dyes, intercalation in layered materials and control of nanoparticle growth. The β measurements of the [MnPS3/DAZOP] nanoparticles and of pure DAZOP iodide were performed by harmonic light scattering at 1.91 μm. The nanoparticles and pure DAZOP iodide were dissolved in chloroform in the presence of PVP.

AB - An entirely different approach for synthesizing nanoparticles exhibiting giant 'molecular' hyperpolarizability (β) values, evidenced by the spontaneous alignment of several hundreds of dipolar chromophores in each particles, was designed. The strategy to engineer these supramolecular assemblies of nonlinear optics (NLO)-phores involves a combination of several areas of chemistry such as J-aggregates of organic dyes, intercalation in layered materials and control of nanoparticle growth. The β measurements of the [MnPS3/DAZOP] nanoparticles and of pure DAZOP iodide were performed by harmonic light scattering at 1.91 μm. The nanoparticles and pure DAZOP iodide were dissolved in chloroform in the presence of PVP.

U2 - 10.1002/adma.200400583

DO - 10.1002/adma.200400583

M3 - Article

AN - SCOPUS:14644443569

SN - 0935-9648

VL - 17

SP - 335

EP - 338

JO - Advanced Materials

JF - Advanced Materials

IS - 3

ER -

J-aggregated dye-MnPS3 hybrid nanoparticles with giant quadratic optical nonlinearity

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J-aggregated dye-MnPS₃ hybrid nanoparticles with giant quadratic optical nonlinearity