@inproceedings{cee37a39a7074b25967c830a189d3f89,
title = "Lithium dendrite inhibition on post-charge anode surface: The kinetics role",
abstract = "We report experiments and molecular dynamics calculations on the kinetics of electrodeposited lithium dendrites relaxation as a function of temperature and time We found that the experimental average length of dendrite population decays via stretched exponential functions of time toward limiting values that depend inversely on temperature. The experimental activation energy derived from initial rates as Ea\textasciitilde{} 6-7 kcal/mole, which is closely matched by MD calculations, based on the ReaxFF force field for metallic lithium. Simulations reveal that relaxation proceeds in several steps via increasingly larger activation barriers. Incomplete relaxation at lower temperatures is therefore interpreted a manifestation of cooperative atomic motions into discrete topologies that frustrate monotonie progress by 'caging'.",
keywords = "Activation Energy, Annealing., Kinetics, Lithium Dendrites",
author = "Asgliar Aryanfar and Tao Cheng and Merinov, \{Boris V.\} and Goddard, \{William A.\} and Colussi, \{Agustin J.\} and Hoffmann, \{Michael R.\}",
note = "Publisher Copyright: {\textcopyright} 2015 Materials Research Society.; 2015 MRS Spring Meeting ; Conference date: 06-04-2015 Through 10-04-2015",
year = "2015",
month = jan,
day = "1",
doi = "10.1557/opl.2015.745",
language = "English",
series = "Materials Research Society Symposium Proceedings",
publisher = "Materials Research Society",
pages = "31--39",
editor = "Jiangyu Li and Haleh Ardebili and Kaiyang Zeng and John Huber",
booktitle = "Mechanics of Energy Storage and Conversion - Batteries, Thermoelectrics and Fuel Cell",
}