Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate

Quentin Benito; Cristina M. Balogh; Hani El Moll; Thierry Gacoin; Marie Cordier; Aydar Rakhmatullin; Camille Latouche; Charlotte Martineau-Corcos; Sandrine Perruchas

doi:10.1002/chem.201804377

Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate

Quentin Benito
, Cristina M. Balogh
, Hani El Moll
, Thierry Gacoin
, Marie Cordier
, Aydar Rakhmatullin
, Camille Latouche
, Charlotte Martineau-Corcos
, Sandrine Perruchas

CNRS
UPR 3079
Institut des Matériaux de Nantes
Institut Lavoisier de Versailles

Research output: Contribution to journal › Article › peer-review

Abstract

A copper iodide complex coordinated by three phosphine ligands with the formula [Cu₂I₂(Ph₂PC₂(C₆H₄)C₂PPh₂)₃] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.

Original language	English
Pages (from-to)	18868-18872
Number of pages	5
Journal	Chemistry - A European Journal
Volume	24
Issue number	71
DOIs	https://doi.org/10.1002/chem.201804377
Publication status	Published - 17 Dec 2018

Keywords

copper
luminescence
molecular rotor
solvatochromism
vapochromism

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10.1002/chem.201804377

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title = "Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate",

abstract = "A copper iodide complex coordinated by three phosphine ligands with the formula [Cu2I2(Ph2PC2(C6H4)C2PPh2)3] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.",

keywords = "copper, luminescence, molecular rotor, solvatochromism, vapochromism",

author = "Quentin Benito and Balogh, \{Cristina M.\} and \{El Moll\}, Hani and Thierry Gacoin and Marie Cordier and Aydar Rakhmatullin and Camille Latouche and Charlotte Martineau-Corcos and Sandrine Perruchas",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = dec,

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doi = "10.1002/chem.201804377",

language = "English",

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T1 - Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate

AU - Benito, Quentin

AU - Balogh, Cristina M.

AU - El Moll, Hani

AU - Gacoin, Thierry

AU - Cordier, Marie

AU - Rakhmatullin, Aydar

AU - Latouche, Camille

AU - Martineau-Corcos, Charlotte

AU - Perruchas, Sandrine

PY - 2018/12/17

Y1 - 2018/12/17

N2 - A copper iodide complex coordinated by three phosphine ligands with the formula [Cu2I2(Ph2PC2(C6H4)C2PPh2)3] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.

AB - A copper iodide complex coordinated by three phosphine ligands with the formula [Cu2I2(Ph2PC2(C6H4)C2PPh2)3] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.

KW - copper

KW - luminescence

KW - molecular rotor

KW - solvatochromism

KW - vapochromism

U2 - 10.1002/chem.201804377

DO - 10.1002/chem.201804377

M3 - Article

C2 - 30259587

AN - SCOPUS:85056723760

SN - 0947-6539

VL - 24

SP - 18868

EP - 18872

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 71

ER -

Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate

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Keywords

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