Manipulating the Topological Interface by Molecular Adsorbates: Adsorption of Co-Phthalocyanine on Bi2Se3

Marco Caputo; Mirko Panighel; Simone Lisi; Lama Khalil; Giovanni Di Santo; Evangelos Papalazarou; Andrzej Hruban; Marcin Konczykowski; Lia Krusin-Elbaum; Ziya S. Aliev; Mahammad B. Babanly; Mikhail M. Otrokov; Antonio Politano; Evgueni V. Chulkov; Andrés Arnau; Vera Marinova; Pranab K. Das; Jun Fujii; Ivana Vobornik; Luca Perfetti; Aitor Mugarza; Andrea Goldoni; Marino Marsi

doi:10.1021/acs.nanolett.5b02635

Manipulating the Topological Interface by Molecular Adsorbates: Adsorption of Co-Phthalocyanine on Bi₂Se₃

Marco Caputo
, Mirko Panighel
, Simone Lisi
, Lama Khalil
, Giovanni Di Santo
, Evangelos Papalazarou
, Andrzej Hruban
, Marcin Konczykowski
, Lia Krusin-Elbaum
, Ziya S. Aliev
, Mahammad B. Babanly
, Mikhail M. Otrokov
, Antonio Politano
, Evgueni V. Chulkov
, Andrés Arnau
, Vera Marinova
, Pranab K. Das
, Jun Fujii
, Ivana Vobornik
, Luca Perfetti

Aitor Mugarza, Andrea Goldoni, Marino Marsi

Laboratoire de Physique des Solides
Laboratory Micro and Nano-Carbon
Nova Gorica Univ., Slovenia and Sincrotrone ELETTRA
University of Sheffield
Dipartimento di Fisica
Centre national de la recherche scientifique
Synchrotron SOLEIL
Łukasiewicz Research Network - Institute of Microelectronics and Photonics
Université Paris-Saclay
Department of Physics
The City College of New York
Institute of Catalisys and Inorganic Chemistry
Azerbaijan Academy of Sciences
Nano-Bio Spectroscopy Group, Departamento Física de Materiales, DIPC
Tomsk State University
Dipartimento di Fisica
University of Calabria
Department of Materials Physics
University of the Basque Country
Centro de Física de Materiales (CFM)
EHU
Saint Petersburg State University
Institute of Optical Materials and Technologies
IOM-CNR
Abdus Salam International Centre for Theoretical Physics
Pompeu Fabra University (UPF)

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

Topological insulators are a promising class of materials for applications in the field of spintronics. New perspectives in this field can arise from interfacing metal-organic molecules with the topological insulator spin-momentum locked surface states, which can be perturbed enhancing or suppressing spintronics-relevant properties such as spin coherence. Here we show results from an angle-resolved photemission spectroscopy (ARPES) and scanning tunnelling microscopy (STM) study of the prototypical cobalt phthalocyanine (CoPc)/Bi₂Se₃ interface. We demonstrate that that the hybrid interface can act on the topological protection of the surface and bury the Dirac cone below the first quintuple layer.

Original language	English
Pages (from-to)	3409-3414
Number of pages	6
Journal	Nano Letters
Volume	16
Issue number	6
DOIs	https://doi.org/10.1021/acs.nanolett.5b02635
Publication status	Published - 8 Jun 2016
Externally published	Yes

Keywords

ARPES
Dirac cone
Topological insulator
charge transfer
phthalocyanine
surface states

Access to Document

10.1021/acs.nanolett.5b02635

Cite this

Caputo, M., Panighel, M., Lisi, S., Khalil, L., Santo, G. D., Papalazarou, E., Hruban, A., Konczykowski, M., Krusin-Elbaum, L., Aliev, Z. S., Babanly, M. B., Otrokov, M. M., Politano, A., Chulkov, E. V., Arnau, A., Marinova, V., Das, P. K., Fujii, J., Vobornik, I., ... Marsi, M. (2016). Manipulating the Topological Interface by Molecular Adsorbates: Adsorption of Co-Phthalocyanine on Bi₂Se₃. Nano Letters, 16(6), 3409-3414. https://doi.org/10.1021/acs.nanolett.5b02635

@article{f599ee1b8ed64717be12cfeaf8370f21,

title = "Manipulating the Topological Interface by Molecular Adsorbates: Adsorption of Co-Phthalocyanine on Bi2Se3",

abstract = "Topological insulators are a promising class of materials for applications in the field of spintronics. New perspectives in this field can arise from interfacing metal-organic molecules with the topological insulator spin-momentum locked surface states, which can be perturbed enhancing or suppressing spintronics-relevant properties such as spin coherence. Here we show results from an angle-resolved photemission spectroscopy (ARPES) and scanning tunnelling microscopy (STM) study of the prototypical cobalt phthalocyanine (CoPc)/Bi2Se3 interface. We demonstrate that that the hybrid interface can act on the topological protection of the surface and bury the Dirac cone below the first quintuple layer.",

keywords = "ARPES, Dirac cone, Topological insulator, charge transfer, phthalocyanine, surface states",

author = "Marco Caputo and Mirko Panighel and Simone Lisi and Lama Khalil and Santo, \{Giovanni Di\} and Evangelos Papalazarou and Andrzej Hruban and Marcin Konczykowski and Lia Krusin-Elbaum and Aliev, \{Ziya S.\} and Babanly, \{Mahammad B.\} and Otrokov, \{Mikhail M.\} and Antonio Politano and Chulkov, \{Evgueni V.\} and Andr{\'e}s Arnau and Vera Marinova and Das, \{Pranab K.\} and Jun Fujii and Ivana Vobornik and Luca Perfetti and Aitor Mugarza and Andrea Goldoni and Marino Marsi",

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doi = "10.1021/acs.nanolett.5b02635",

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Caputo, M, Panighel, M, Lisi, S, Khalil, L, Santo, GD, Papalazarou, E, Hruban, A, Konczykowski, M, Krusin-Elbaum, L, Aliev, ZS, Babanly, MB, Otrokov, MM, Politano, A, Chulkov, EV, Arnau, A, Marinova, V, Das, PK, Fujii, J, Vobornik, I, Perfetti, L, Mugarza, A, Goldoni, A & Marsi, M 2016, 'Manipulating the Topological Interface by Molecular Adsorbates: Adsorption of Co-Phthalocyanine on Bi₂Se₃', Nano Letters, vol. 16, no. 6, pp. 3409-3414. https://doi.org/10.1021/acs.nanolett.5b02635

TY - JOUR

T1 - Manipulating the Topological Interface by Molecular Adsorbates

T2 - Adsorption of Co-Phthalocyanine on Bi2Se3

AU - Caputo, Marco

AU - Panighel, Mirko

AU - Lisi, Simone

AU - Khalil, Lama

AU - Santo, Giovanni Di

AU - Papalazarou, Evangelos

AU - Hruban, Andrzej

AU - Konczykowski, Marcin

AU - Krusin-Elbaum, Lia

AU - Aliev, Ziya S.

AU - Babanly, Mahammad B.

AU - Otrokov, Mikhail M.

AU - Politano, Antonio

AU - Chulkov, Evgueni V.

AU - Arnau, Andrés

AU - Marinova, Vera

AU - Das, Pranab K.

AU - Fujii, Jun

AU - Vobornik, Ivana

AU - Perfetti, Luca

AU - Mugarza, Aitor

AU - Goldoni, Andrea

AU - Marsi, Marino

PY - 2016/6/8

Y1 - 2016/6/8

N2 - Topological insulators are a promising class of materials for applications in the field of spintronics. New perspectives in this field can arise from interfacing metal-organic molecules with the topological insulator spin-momentum locked surface states, which can be perturbed enhancing or suppressing spintronics-relevant properties such as spin coherence. Here we show results from an angle-resolved photemission spectroscopy (ARPES) and scanning tunnelling microscopy (STM) study of the prototypical cobalt phthalocyanine (CoPc)/Bi2Se3 interface. We demonstrate that that the hybrid interface can act on the topological protection of the surface and bury the Dirac cone below the first quintuple layer.

AB - Topological insulators are a promising class of materials for applications in the field of spintronics. New perspectives in this field can arise from interfacing metal-organic molecules with the topological insulator spin-momentum locked surface states, which can be perturbed enhancing or suppressing spintronics-relevant properties such as spin coherence. Here we show results from an angle-resolved photemission spectroscopy (ARPES) and scanning tunnelling microscopy (STM) study of the prototypical cobalt phthalocyanine (CoPc)/Bi2Se3 interface. We demonstrate that that the hybrid interface can act on the topological protection of the surface and bury the Dirac cone below the first quintuple layer.

KW - ARPES

KW - Dirac cone

KW - Topological insulator

KW - charge transfer

KW - phthalocyanine

KW - surface states

U2 - 10.1021/acs.nanolett.5b02635

DO - 10.1021/acs.nanolett.5b02635

M3 - Article

AN - SCOPUS:84973664362

SN - 1530-6984

VL - 16

SP - 3409

EP - 3414

JO - Nano Letters

JF - Nano Letters

IS - 6