Modification of the carrier mobility of conducting PF-EP polymer by formation of their composites with thiophene derivatives

Sergey D. Tokarev; Yury V. Fedorov; Anna A. Moiseeva; Gediminas Jonusauskas; Dmitry A. Lypenko; Alexey E. Aleksandrov; Alexey R. Tameev; Eugene I. Maltsev; Galina I. Nosova; Elena V. Zhukova; Olga A. Fedorova

doi:10.1016/j.orgel.2019.105586

Modification of the carrier mobility of conducting PF-EP polymer by formation of their composites with thiophene derivatives

Sergey D. Tokarev
, Yury V. Fedorov
, Anna A. Moiseeva
, Gediminas Jonusauskas
, Dmitry A. Lypenko
, Alexey E. Aleksandrov
, Alexey R. Tameev
, Eugene I. Maltsev
, Galina I. Nosova
, Elena V. Zhukova
, Olga A. Fedorova

Moscow State University
Russian Academy of Sciences
Univ. Bordeaux
Russian Academy of Sciences
Institute of Macromolecular Compounds, Russian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

In the paper we present synthesis and characterization of new donor–acceptor thiophene derivatives (TDs) containing vinylbenzo[d]thiazole, vinylpyridine and 1H-imidazo[4,5-f][1,10]phenanthroline residues. Using CELIV method, electron and hole mobility have been studied in the polymer layers based on poly [9,9-bis(6-diethoxyl-phosphorylhexyl)fluorine] (PF-EP) doped with the TDs. Polymer light-emitting diodes (PLEDs) containing newly synthesized polyfluorene (PF) as emitting layers and PF-EP/TD composites as electron transporting layers show higher brightness at 15V as compared with TD free PF-EP.

Original language	English
Article number	105586
Journal	Organic Electronics
Volume	78
DOIs	https://doi.org/10.1016/j.orgel.2019.105586
Publication status	Published - 1 Mar 2020
Externally published	Yes

Keywords

Ambipolar charge transport
Conducting polymer
Molecular semiconductor
Structure–property relationship
Thiophene derivative

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10.1016/j.orgel.2019.105586

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Tokarev, S. D., Fedorov, Y. V., Moiseeva, A. A., Jonusauskas, G., Lypenko, D. A., Aleksandrov, A. E., Tameev, A. R., Maltsev, E. I., Nosova, G. I., Zhukova, E. V., & Fedorova, O. A. (2020). Modification of the carrier mobility of conducting PF-EP polymer by formation of their composites with thiophene derivatives. Organic Electronics, 78, Article 105586. https://doi.org/10.1016/j.orgel.2019.105586

@article{90e54c0cb2914826b1eab1e96b0b42cd,

title = "Modification of the carrier mobility of conducting PF-EP polymer by formation of their composites with thiophene derivatives",

abstract = "In the paper we present synthesis and characterization of new donor–acceptor thiophene derivatives (TDs) containing vinylbenzo[d]thiazole, vinylpyridine and 1H-imidazo[4,5-f][1,10]phenanthroline residues. Using CELIV method, electron and hole mobility have been studied in the polymer layers based on poly [9,9-bis(6-diethoxyl-phosphorylhexyl)fluorine] (PF-EP) doped with the TDs. Polymer light-emitting diodes (PLEDs) containing newly synthesized polyfluorene (PF) as emitting layers and PF-EP/TD composites as electron transporting layers show higher brightness at 15V as compared with TD free PF-EP.",

keywords = "Ambipolar charge transport, Conducting polymer, Molecular semiconductor, Structure–property relationship, Thiophene derivative",

author = "Tokarev, \{Sergey D.\} and Fedorov, \{Yury V.\} and Moiseeva, \{Anna A.\} and Gediminas Jonusauskas and Lypenko, \{Dmitry A.\} and Aleksandrov, \{Alexey E.\} and Tameev, \{Alexey R.\} and Maltsev, \{Eugene I.\} and Nosova, \{Galina I.\} and Zhukova, \{Elena V.\} and Fedorova, \{Olga A.\}",

note = "Publisher Copyright: {\textcopyright} 2019",

year = "2020",

month = mar,

day = "1",

doi = "10.1016/j.orgel.2019.105586",

language = "English",

volume = "78",

journal = "Organic Electronics",

issn = "1566-1199",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Modification of the carrier mobility of conducting PF-EP polymer by formation of their composites with thiophene derivatives

AU - Tokarev, Sergey D.

AU - Fedorov, Yury V.

AU - Moiseeva, Anna A.

AU - Jonusauskas, Gediminas

AU - Lypenko, Dmitry A.

AU - Aleksandrov, Alexey E.

AU - Tameev, Alexey R.

AU - Maltsev, Eugene I.

AU - Nosova, Galina I.

AU - Zhukova, Elena V.

AU - Fedorova, Olga A.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - In the paper we present synthesis and characterization of new donor–acceptor thiophene derivatives (TDs) containing vinylbenzo[d]thiazole, vinylpyridine and 1H-imidazo[4,5-f][1,10]phenanthroline residues. Using CELIV method, electron and hole mobility have been studied in the polymer layers based on poly [9,9-bis(6-diethoxyl-phosphorylhexyl)fluorine] (PF-EP) doped with the TDs. Polymer light-emitting diodes (PLEDs) containing newly synthesized polyfluorene (PF) as emitting layers and PF-EP/TD composites as electron transporting layers show higher brightness at 15V as compared with TD free PF-EP.

AB - In the paper we present synthesis and characterization of new donor–acceptor thiophene derivatives (TDs) containing vinylbenzo[d]thiazole, vinylpyridine and 1H-imidazo[4,5-f][1,10]phenanthroline residues. Using CELIV method, electron and hole mobility have been studied in the polymer layers based on poly [9,9-bis(6-diethoxyl-phosphorylhexyl)fluorine] (PF-EP) doped with the TDs. Polymer light-emitting diodes (PLEDs) containing newly synthesized polyfluorene (PF) as emitting layers and PF-EP/TD composites as electron transporting layers show higher brightness at 15V as compared with TD free PF-EP.

KW - Ambipolar charge transport

KW - Conducting polymer

KW - Molecular semiconductor

KW - Structure–property relationship

KW - Thiophene derivative

UR - https://www.scopus.com/pages/publications/85076507143

U2 - 10.1016/j.orgel.2019.105586

DO - 10.1016/j.orgel.2019.105586

M3 - Article

AN - SCOPUS:85076507143

SN - 1566-1199

VL - 78

JO - Organic Electronics

JF - Organic Electronics

M1 - 105586

ER -

Modification of the carrier mobility of conducting PF-EP polymer by formation of their composites with thiophene derivatives

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Keywords

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