Nef-Perkow-Mumm Cascade towards Imido Phosphate Derivatives

Aurélie Dos Santos; Marie Cordier; Laurent El Kaïm

doi:10.1055/s-0036-1590856

Nef-Perkow-Mumm Cascade towards Imido Phosphate Derivatives

Aurélie Dos Santos
, Marie Cordier
, Laurent El Kaïm

Université Paris-Saclay

Research output: Contribution to journal › Article › peer-review

Abstract

A one-pot, four-component synthesis of imido phosphates has been achieved using a Nef-Perkow sequence followed by addition of carboxylic acid derivatives. The final imido moiety is formed via a Mumm rearrangement of an intermediate imidate.

Original language	English
Pages (from-to)	2637-2641
Number of pages	5
Journal	Synlett
Volume	28
Issue number	19
DOIs	https://doi.org/10.1055/s-0036-1590856
Publication status	Published - 1 Dec 2017
Externally published	Yes

Keywords

Mumm rearrangement
Nef reaction
Perkow reaction
isocyanide
keteneimine
vinyl phosphate

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10.1055/s-0036-1590856

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@article{bc44d09a94ca4294b83b7ef1669849c3,

title = "Nef-Perkow-Mumm Cascade towards Imido Phosphate Derivatives",

abstract = "A one-pot, four-component synthesis of imido phosphates has been achieved using a Nef-Perkow sequence followed by addition of carboxylic acid derivatives. The final imido moiety is formed via a Mumm rearrangement of an intermediate imidate.",

keywords = "Mumm rearrangement, Nef reaction, Perkow reaction, isocyanide, keteneimine, vinyl phosphate",

author = "\{Dos Santos\}, Aur{\'e}lie and Marie Cordier and \{El Ka{\"i}m\}, Laurent",

year = "2017",

month = dec,

day = "1",

doi = "10.1055/s-0036-1590856",

language = "English",

volume = "28",

pages = "2637--2641",

journal = "Synlett",

issn = "0936-5214",

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TY - JOUR

T1 - Nef-Perkow-Mumm Cascade towards Imido Phosphate Derivatives

AU - Dos Santos, Aurélie

AU - Cordier, Marie

AU - El Kaïm, Laurent

PY - 2017/12/1

Y1 - 2017/12/1

N2 - A one-pot, four-component synthesis of imido phosphates has been achieved using a Nef-Perkow sequence followed by addition of carboxylic acid derivatives. The final imido moiety is formed via a Mumm rearrangement of an intermediate imidate.

AB - A one-pot, four-component synthesis of imido phosphates has been achieved using a Nef-Perkow sequence followed by addition of carboxylic acid derivatives. The final imido moiety is formed via a Mumm rearrangement of an intermediate imidate.

KW - Mumm rearrangement

KW - Nef reaction

KW - Perkow reaction

KW - isocyanide

KW - keteneimine

KW - vinyl phosphate

U2 - 10.1055/s-0036-1590856

DO - 10.1055/s-0036-1590856

M3 - Article

AN - SCOPUS:85027970238

SN - 0936-5214

VL - 28

SP - 2637

EP - 2641

JO - Synlett

JF - Synlett

IS - 19

ER -

Nef-Perkow-Mumm Cascade towards Imido Phosphate Derivatives

Abstract

Keywords

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