New efficient preparation of arylzinc compounds from aryl halides using cobalt catalysis and sacrificial anode process

Corinne Gosmini; Yolande Rollin; Jean Yves Nédélec; Jacques Périchon

doi:10.1021/jo000459b

New efficient preparation of arylzinc compounds from aryl halides using cobalt catalysis and sacrificial anode process

Corinne Gosmini, Yolande Rollin, Jean Yves Nédélec, Jacques Périchon

Institut de Chimie et des Matériaux de Paris Est, CNRS UPEC/UMR 7182

Research output: Contribution to journal › Article › peer-review

Abstract

Electroreduction of aryl-chlorides or -bromides in an electrochemical cell fitted with a sacrificial zinc anode and in the presence of cobalt halide associated with pyridine as ligand in DMF or acetonitrile as solvent affords the corresponding organozinc species in good yields.

Original language	English
Pages (from-to)	6024-6026
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	65
Issue number	19
DOIs	https://doi.org/10.1021/jo000459b
Publication status	Published - 22 Sept 2000
Externally published	Yes

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@article{b8f27f0996aa4430a21df6a3f2812fa6,

title = "New efficient preparation of arylzinc compounds from aryl halides using cobalt catalysis and sacrificial anode process",

abstract = "Electroreduction of aryl-chlorides or -bromides in an electrochemical cell fitted with a sacrificial zinc anode and in the presence of cobalt halide associated with pyridine as ligand in DMF or acetonitrile as solvent affords the corresponding organozinc species in good yields.",

author = "Corinne Gosmini and Yolande Rollin and N{\'e}d{\'e}lec, \{Jean Yves\} and Jacques P{\'e}richon",

year = "2000",

month = sep,

day = "22",

doi = "10.1021/jo000459b",

language = "English",

volume = "65",

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journal = "Journal of Organic Chemistry",

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T1 - New efficient preparation of arylzinc compounds from aryl halides using cobalt catalysis and sacrificial anode process

AU - Gosmini, Corinne

AU - Rollin, Yolande

AU - Nédélec, Jean Yves

AU - Périchon, Jacques

PY - 2000/9/22

Y1 - 2000/9/22

N2 - Electroreduction of aryl-chlorides or -bromides in an electrochemical cell fitted with a sacrificial zinc anode and in the presence of cobalt halide associated with pyridine as ligand in DMF or acetonitrile as solvent affords the corresponding organozinc species in good yields.

AB - Electroreduction of aryl-chlorides or -bromides in an electrochemical cell fitted with a sacrificial zinc anode and in the presence of cobalt halide associated with pyridine as ligand in DMF or acetonitrile as solvent affords the corresponding organozinc species in good yields.

U2 - 10.1021/jo000459b

DO - 10.1021/jo000459b

M3 - Article

AN - SCOPUS:0034703334

SN - 0022-3263

VL - 65

SP - 6024

EP - 6026

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 19

ER -

New efficient preparation of arylzinc compounds from aryl halides using cobalt catalysis and sacrificial anode process

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