Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) 5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph 2)]

Duncan Carmichael; Peter B. Hitchcock; John F. Nixon; François Mathey; Alan Pidcock

doi:10.1039/C39860000762

Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) ₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph ₂)]

Duncan Carmichael
, Peter B. Hitchcock
, John F. Nixon
, François Mathey
, Alan Pidcock

University of Sussex
Laboratoire CNRS-SNPE
Lancashire Polytechnic

Research output: Contribution to journal › Article › peer-review

Abstract

The strain phosphirene ring in [W(CO)₅(PhPC₂Ph ₂)] readily undergoes insertion of [M(PR₃)₂] fragments (M = Pd, Pt) to give complexes in which phosphorus bridges two different metal atoms.

Original language	English
Pages (from-to)	762-763
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39860000762
Publication status	Published - 1 Jan 1986
Externally published	Yes

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Carmichael, D., Hitchcock, P. B., Nixon, J. F., Mathey, F., & Pidcock, A. (1986). Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) ₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph ₂)]. Journal of the Chemical Society, Chemical Communications, (10), 762-763. https://doi.org/10.1039/C39860000762

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title = "Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) 5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph 2)]",

abstract = "The strain phosphirene ring in [W(CO)5(PhPC2Ph 2)] readily undergoes insertion of [M(PR3)2] fragments (M = Pd, Pt) to give complexes in which phosphorus bridges two different metal atoms.",

author = "Duncan Carmichael and Hitchcock, \{Peter B.\} and Nixon, \{John F.\} and Fran{\c c}ois Mathey and Alan Pidcock",

year = "1986",

month = jan,

day = "1",

doi = "10.1039/C39860000762",

language = "English",

pages = "762--763",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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}

Carmichael, D, Hitchcock, PB, Nixon, JF, Mathey, F & Pidcock, A 1986, 'Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) ₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph ₂)]', Journal of the Chemical Society, Chemical Communications, no. 10, pp. 762-763. https://doi.org/10.1039/C39860000762

Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) ₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph ₂)]. / Carmichael, Duncan; Hitchcock, Peter B.; Nixon, John F. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 10, 01.01.1986, p. 762-763.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Novel insertion of [M(PR3)2] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) 5(PhPC2Ph2)]. Crystal and molecular structure of [PtW(CO)5(PEt3)2(PhPC2Ph 2)]

AU - Carmichael, Duncan

AU - Hitchcock, Peter B.

AU - Nixon, John F.

AU - Mathey, François

AU - Pidcock, Alan

PY - 1986/1/1

Y1 - 1986/1/1

N2 - The strain phosphirene ring in [W(CO)5(PhPC2Ph 2)] readily undergoes insertion of [M(PR3)2] fragments (M = Pd, Pt) to give complexes in which phosphorus bridges two different metal atoms.

AB - The strain phosphirene ring in [W(CO)5(PhPC2Ph 2)] readily undergoes insertion of [M(PR3)2] fragments (M = Pd, Pt) to give complexes in which phosphorus bridges two different metal atoms.

U2 - 10.1039/C39860000762

DO - 10.1039/C39860000762

M3 - Article

AN - SCOPUS:37049085643

SN - 0022-4936

SP - 762

EP - 763

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -

Carmichael D, Hitchcock PB, Nixon JF, Mathey F, Pidcock A. Novel insertion of [M(PR₃)₂] fragments (M = Pd, Pt) into the strained phosphorus-carbon bond of the phosphirene complex [W(CO) ₅(PhPC₂Ph₂)]. Crystal and molecular structure of [PtW(CO)₅(PEt₃)₂(PhPC₂Ph ₂)]. Journal of the Chemical Society, Chemical Communications. 1986 Jan 1;(10):762-763. doi: 10.1039/C39860000762