On the [2,3] sigmatropic rearrangement of allylic nitro compounds

Celia Alameda-Angulo; Béatrice Quiclet-Sire; Elmar Schmidt; Samir Z. Zard

doi:10.1021/ol051196g

On the [2,3] sigmatropic rearrangement of allylic nitro compounds

Celia Alameda-Angulo
, Béatrice Quiclet-Sire
, Elmar Schmidt
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic nitrite.

Original language	English
Pages (from-to)	3489-3492
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	16
DOIs	https://doi.org/10.1021/ol051196g
Publication status	Published - 4 Aug 2005
Externally published	Yes

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@article{f4fa236f19084ff6bfb0e532d5cef677,

title = "On the [2,3] sigmatropic rearrangement of allylic nitro compounds",

abstract = "(Chemical Equation Presented) Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic nitrite.",

author = "Celia Alameda-Angulo and B{\'e}atrice Quiclet-Sire and Elmar Schmidt and Zard, \{Samir Z.\}",

year = "2005",

month = aug,

day = "4",

doi = "10.1021/ol051196g",

language = "English",

volume = "7",

pages = "3489--3492",

journal = "Organic Letters",

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number = "16",

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T1 - On the [2,3] sigmatropic rearrangement of allylic nitro compounds

AU - Alameda-Angulo, Celia

AU - Quiclet-Sire, Béatrice

AU - Schmidt, Elmar

AU - Zard, Samir Z.

PY - 2005/8/4

Y1 - 2005/8/4

N2 - (Chemical Equation Presented) Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic nitrite.

AB - (Chemical Equation Presented) Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic nitrite.

U2 - 10.1021/ol051196g

DO - 10.1021/ol051196g

M3 - Article

AN - SCOPUS:23944456835

SN - 1523-7060

VL - 7

SP - 3489

EP - 3492

JO - Organic Letters

JF - Organic Letters

IS - 16

ER -

On the [2,3] sigmatropic rearrangement of allylic nitro compounds

Abstract

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